Saved in:
Bibliographic Details
Main Authors: Zeng, Xiongzhi, Zhang, Huili, Zhang, Shizheng, Liu, Pei, Linghu, Kehuan, Cui, Jiangyu, Cai, Xiaoxia, Liu, Jie, Li, Zhenyu, Yang, Jinlong
Format: Preprint
Published: 2024
Subjects:
Online Access:https://arxiv.org/abs/2404.14038
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1866913324013191168
author Zeng, Xiongzhi
Zhang, Huili
Zhang, Shizheng
Liu, Pei
Linghu, Kehuan
Cui, Jiangyu
Cai, Xiaoxia
Liu, Jie
Li, Zhenyu
Yang, Jinlong
author_facet Zeng, Xiongzhi
Zhang, Huili
Zhang, Shizheng
Liu, Pei
Linghu, Kehuan
Cui, Jiangyu
Cai, Xiaoxia
Liu, Jie
Li, Zhenyu
Yang, Jinlong
contents Quantum computing is of great potential for chemical system simulations. In this study, we propose an efficient protocol of quantum computer based simulation of chemical systems which enables accurate chemical reaction modeling on noisy intermediate-scale quantum (NISQ) devices. In this protocol, we combine an correlation energy-based active orbital selection, an effective Hamiltonian from the driven similarity renormalization group (DSRG) method, and a noise-resilient wavefunction ansatz. Such a combination gives a quantum resource-efficient way to accurately simulate chemical systems. The power of this protocol is demonstrated by numerical results for systems with up to tens of atoms. Modeling of a Diels-Alder (DA) reaction is also performed on a cloud-based superconducting quantum computer. These results represent an important step forward in realizing quantum utility in the NISQ era.
format Preprint
id arxiv_https___arxiv_org_abs_2404_14038
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Accurate Chemical Reaction Modeling on Noisy Intermediate-Scale Quantum Computers Using a Noise-Resilient Wavefunction Ansatz
Zeng, Xiongzhi
Zhang, Huili
Zhang, Shizheng
Liu, Pei
Linghu, Kehuan
Cui, Jiangyu
Cai, Xiaoxia
Liu, Jie
Li, Zhenyu
Yang, Jinlong
Quantum Physics
Quantum computing is of great potential for chemical system simulations. In this study, we propose an efficient protocol of quantum computer based simulation of chemical systems which enables accurate chemical reaction modeling on noisy intermediate-scale quantum (NISQ) devices. In this protocol, we combine an correlation energy-based active orbital selection, an effective Hamiltonian from the driven similarity renormalization group (DSRG) method, and a noise-resilient wavefunction ansatz. Such a combination gives a quantum resource-efficient way to accurately simulate chemical systems. The power of this protocol is demonstrated by numerical results for systems with up to tens of atoms. Modeling of a Diels-Alder (DA) reaction is also performed on a cloud-based superconducting quantum computer. These results represent an important step forward in realizing quantum utility in the NISQ era.
title Accurate Chemical Reaction Modeling on Noisy Intermediate-Scale Quantum Computers Using a Noise-Resilient Wavefunction Ansatz
topic Quantum Physics
url https://arxiv.org/abs/2404.14038