Comparison of h-BN and graphene layers as grain boundary materials for granular FePt-$\text{L}1_0$ thin films

Fuente: arXiv
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Autori principali: Varaprasad, B. S. D. Ch. S., Xu, Chengchao, Reese, Brandon, Laughlin, David E., Jian-Gang, Zhu
Natura: Preprint
Pubblicazione: 2024
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author Varaprasad, B. S. D. Ch. S.
Xu, Chengchao
Reese, Brandon
Laughlin, David E.
Jian-Gang
Zhu
author_facet Varaprasad, B. S. D. Ch. S.
Xu, Chengchao
Reese, Brandon
Laughlin, David E.
Jian-Gang
Zhu
contents Granular $\text{L}1_0$-FePt thin films with small columnar grains are essential for heat-assisted magnetic recording media. While hexagonal boron nitride(h-BN) has proven effective for promoting columnar FePt grains, we explored multilayer graphene as an alternative grain boundary material leveraging its structural similarity to h-BN. The FePt granular thin films with carbon-based grain boundary materials(GBMs) were deposited by cosputtering on Si/SiO2 substrates with substrate bias at 650°C. The RF bias and high temperature facilitated formation of interlinked graphene nanoribbons wrapping around FePt grains, yielding 7.5 nm diameter, 8 nm height grains with an order parameter of 0.78 and a perpendicular coercivity of 40 kOe. However, the formation of graphene nanoribbons could not effectively promote columnar structures, likely due to co-existing amorphous carbon in grain boundaries. Optimizing deposition to improve graphene grain boundary quality is necessary to realize this 2D material's potential for achieving desirable microstructures for HAMR media.
format Preprint
id arxiv_https___arxiv_org_abs_2404_14290
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Comparison of h-BN and graphene layers as grain boundary materials for granular FePt-$\text{L}1_0$ thin films
Varaprasad, B. S. D. Ch. S.
Xu, Chengchao
Reese, Brandon
Laughlin, David E.
Jian-Gang
Zhu
Materials Science
Applied Physics
Granular $\text{L}1_0$-FePt thin films with small columnar grains are essential for heat-assisted magnetic recording media. While hexagonal boron nitride(h-BN) has proven effective for promoting columnar FePt grains, we explored multilayer graphene as an alternative grain boundary material leveraging its structural similarity to h-BN. The FePt granular thin films with carbon-based grain boundary materials(GBMs) were deposited by cosputtering on Si/SiO2 substrates with substrate bias at 650°C. The RF bias and high temperature facilitated formation of interlinked graphene nanoribbons wrapping around FePt grains, yielding 7.5 nm diameter, 8 nm height grains with an order parameter of 0.78 and a perpendicular coercivity of 40 kOe. However, the formation of graphene nanoribbons could not effectively promote columnar structures, likely due to co-existing amorphous carbon in grain boundaries. Optimizing deposition to improve graphene grain boundary quality is necessary to realize this 2D material's potential for achieving desirable microstructures for HAMR media.
title Comparison of h-BN and graphene layers as grain boundary materials for granular FePt-$\text{L}1_0$ thin films
topic Materials Science
Applied Physics
url https://arxiv.org/abs/2404.14290