Salvato in:
| Autori principali: | , |
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| Natura: | Preprint |
| Pubblicazione: |
2024
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| Soggetti: | |
| Accesso online: | https://arxiv.org/abs/2404.16453 |
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Sommario:
- We investigate analytically the performance of many-body energy functionals, derived respectively by Klein and Luttinger and Ward, at different levels of diagrammatic approximations, ranging from second Born, to GW, to the so-called T-matrix, for the calculation of total energies and potential energy surfaces. We benchmark our theoretical results on the extended two-site Hubbard model, which is analytically solvable and for which several exact properties can be calculated. Despite its simplicity, this model displays the physics of strongly correlated electrons: it is prototypical of the H$_2$ dissociation, a notoriously difficult problem to solve accurately for the majority of mean-field based approaches. We show that both functionals exhibit good to excellent variational properties, particularly in the case of the Luttinger-Ward one, which is in close agreement with fully self-consistent calculations, and elucidate the relation between the accuracy of the results and the different input one-body Green's functions. Provided that these are wisely chosen, we show how the Luttinger-Ward functional can be used as a computationally inexpensive alternative to fully self-consistent many-body calculations, without sacrificing the precision of the results obtained. Furthermore, in virtue of this accuracy, we argue that this functional can also be used to rank different many-body approximations at different regimes of electronic correlation, once again bypassing the need for self-consistency.