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Main Authors: Wang, Feilong, Ou, Qiongrong, Zhang, Shuyu
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2404.17905
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author Wang, Feilong
Ou, Qiongrong
Zhang, Shuyu
author_facet Wang, Feilong
Ou, Qiongrong
Zhang, Shuyu
contents The luminescent mechanism of nano-sized materials with indirect bandgap and parity-forbidden transition has always been a critical issue in breaking through bottlenecks in traditional luminescent materials. The lack of understanding has resulted in great disputes regarding the origin of fluorescence in weak-transition nanocrystals (NCs). This paper proposes a new physical luminescence model, named as localized state-induced enhanced emission (LIEE), i.e., localized processes induced by size-limitation or partial doping, to explain the anomalous luminescence from non-luminescent state to luminescent state in various perovskite nanocrystals with indirect/direct bandgap or parity-forbidden transition. These findings provide a theoretical viewpoint to design efficient lead-free perovskite NCs and promote the development of fast optical transitions in luminescent materials.
format Preprint
id arxiv_https___arxiv_org_abs_2404_17905
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Localized State-Induced Enhanced Emission in Perovskite Nanocrystals
Wang, Feilong
Ou, Qiongrong
Zhang, Shuyu
Materials Science
Mesoscale and Nanoscale Physics
The luminescent mechanism of nano-sized materials with indirect bandgap and parity-forbidden transition has always been a critical issue in breaking through bottlenecks in traditional luminescent materials. The lack of understanding has resulted in great disputes regarding the origin of fluorescence in weak-transition nanocrystals (NCs). This paper proposes a new physical luminescence model, named as localized state-induced enhanced emission (LIEE), i.e., localized processes induced by size-limitation or partial doping, to explain the anomalous luminescence from non-luminescent state to luminescent state in various perovskite nanocrystals with indirect/direct bandgap or parity-forbidden transition. These findings provide a theoretical viewpoint to design efficient lead-free perovskite NCs and promote the development of fast optical transitions in luminescent materials.
title Localized State-Induced Enhanced Emission in Perovskite Nanocrystals
topic Materials Science
Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2404.17905