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| Main Authors: | , , |
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| Format: | Preprint |
| Published: |
2024
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2404.17905 |
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Table of Contents:
- The luminescent mechanism of nano-sized materials with indirect bandgap and parity-forbidden transition has always been a critical issue in breaking through bottlenecks in traditional luminescent materials. The lack of understanding has resulted in great disputes regarding the origin of fluorescence in weak-transition nanocrystals (NCs). This paper proposes a new physical luminescence model, named as localized state-induced enhanced emission (LIEE), i.e., localized processes induced by size-limitation or partial doping, to explain the anomalous luminescence from non-luminescent state to luminescent state in various perovskite nanocrystals with indirect/direct bandgap or parity-forbidden transition. These findings provide a theoretical viewpoint to design efficient lead-free perovskite NCs and promote the development of fast optical transitions in luminescent materials.