Enhancing Ionic Conductivity of ceramic Na3Zr2Si2PO12 via NaI Substitution

Fuente: arXiv
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Main Authors: Sekhar, Aditya, Lilani, Nikesh, Singh, M. Dinachandra
Format: Preprint
Published: 2024
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author Sekhar, Aditya
Lilani, Nikesh
Singh, M. Dinachandra
author_facet Sekhar, Aditya
Lilani, Nikesh
Singh, M. Dinachandra
contents The high ionic conducting sodium superionic conductor Na3Zr2Si2PO12 -NaI composites have been prepared successfully via solid state reaction route. As the NaI content increases, the ionic conductivity significantly changes. The composites with 4% NaI show a maximum ionic conductivity of ~ 3 x 10-4 Ω-1cm-1 at 200oC which is one order of magnitude rise as compared to pristine sample. Further crystal structure and surface morphology also reveal the formation of a glassy phase due to the presence of Na-Si-P-O-I interaction.
format Preprint
id arxiv_https___arxiv_org_abs_2405_02442
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Enhancing Ionic Conductivity of ceramic Na3Zr2Si2PO12 via NaI Substitution
Sekhar, Aditya
Lilani, Nikesh
Singh, M. Dinachandra
Materials Science
The high ionic conducting sodium superionic conductor Na3Zr2Si2PO12 -NaI composites have been prepared successfully via solid state reaction route. As the NaI content increases, the ionic conductivity significantly changes. The composites with 4% NaI show a maximum ionic conductivity of ~ 3 x 10-4 Ω-1cm-1 at 200oC which is one order of magnitude rise as compared to pristine sample. Further crystal structure and surface morphology also reveal the formation of a glassy phase due to the presence of Na-Si-P-O-I interaction.
title Enhancing Ionic Conductivity of ceramic Na3Zr2Si2PO12 via NaI Substitution
topic Materials Science
url https://arxiv.org/abs/2405.02442