Magnetic evolution of Cr$_2$Te$_3$ epitaxially grown on graphene with post-growth annealing

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Main Authors: Guillet, Quentin, Boukari, Hervé, Choueikani, Fadi, Ohresser, Philippe, Ouerghi, Abdelkarim, Mesple, Florie, Renard, Vincent T., Jacquot, Jean-François, Jalabert, Denis, Vergnaud, Céline, Bonell, Frédéric, Marty, Alain, Jamet, Matthieu
Format: Preprint
Published: 2024
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author Guillet, Quentin
Boukari, Hervé
Choueikani, Fadi
Ohresser, Philippe
Ouerghi, Abdelkarim
Mesple, Florie
Renard, Vincent T.
Jacquot, Jean-François
Jalabert, Denis
Vergnaud, Céline
Bonell, Frédéric
Marty, Alain
Jamet, Matthieu
author_facet Guillet, Quentin
Boukari, Hervé
Choueikani, Fadi
Ohresser, Philippe
Ouerghi, Abdelkarim
Mesple, Florie
Renard, Vincent T.
Jacquot, Jean-François
Jalabert, Denis
Vergnaud, Céline
Bonell, Frédéric
Marty, Alain
Jamet, Matthieu
contents Two-dimensional and van der Waals ferromagnets are ideal platform to study low dimensional magnetism and proximity effects in van der Waals heterostructures. Their ultimate two dimensional character offers also the opportunity to easily adjust their magnetic properties using strain or electric fields. Among 2D ferromagnets, the Cr$_{1+x}$Te$_2$ compounds with $x$=0-1 are very promising because their magnetic properties depend on the amount of self-intercalated Cr atoms between pure CrTe$_2$ layers and the Curie temperature (T$_C$) can reach room temperature for certain compositions. Here, we investigate the evolution of the composition, structural and magnetic properties of thin Cr$_{1.33}$Te$_2$ (Cr$_2$Te$_3$) films epitaxially grown on graphene upon annealing. We observe a transition above 450°C from the Cr$_{1.33}$Te$_2$ phase with perpendicular magnetic anisotropy and a T$_C$ of 180 K to a composition close to Cr$_{1.39}$Te$_2$ with in-plane magnetic anisotropy and a T$_C$ of 240-250 K. This phase remains stable up to 650°C above which a pure Cr film starts to form. This work demonstrates the complex interplay between intercalated Cr, lattice parameters and magnetic properties in Cr$_{1+x}$Te$_2$ compounds.
format Preprint
id arxiv_https___arxiv_org_abs_2405_05689
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Magnetic evolution of Cr$_2$Te$_3$ epitaxially grown on graphene with post-growth annealing
Guillet, Quentin
Boukari, Hervé
Choueikani, Fadi
Ohresser, Philippe
Ouerghi, Abdelkarim
Mesple, Florie
Renard, Vincent T.
Jacquot, Jean-François
Jalabert, Denis
Vergnaud, Céline
Bonell, Frédéric
Marty, Alain
Jamet, Matthieu
Materials Science
Two-dimensional and van der Waals ferromagnets are ideal platform to study low dimensional magnetism and proximity effects in van der Waals heterostructures. Their ultimate two dimensional character offers also the opportunity to easily adjust their magnetic properties using strain or electric fields. Among 2D ferromagnets, the Cr$_{1+x}$Te$_2$ compounds with $x$=0-1 are very promising because their magnetic properties depend on the amount of self-intercalated Cr atoms between pure CrTe$_2$ layers and the Curie temperature (T$_C$) can reach room temperature for certain compositions. Here, we investigate the evolution of the composition, structural and magnetic properties of thin Cr$_{1.33}$Te$_2$ (Cr$_2$Te$_3$) films epitaxially grown on graphene upon annealing. We observe a transition above 450°C from the Cr$_{1.33}$Te$_2$ phase with perpendicular magnetic anisotropy and a T$_C$ of 180 K to a composition close to Cr$_{1.39}$Te$_2$ with in-plane magnetic anisotropy and a T$_C$ of 240-250 K. This phase remains stable up to 650°C above which a pure Cr film starts to form. This work demonstrates the complex interplay between intercalated Cr, lattice parameters and magnetic properties in Cr$_{1+x}$Te$_2$ compounds.
title Magnetic evolution of Cr$_2$Te$_3$ epitaxially grown on graphene with post-growth annealing
topic Materials Science
url https://arxiv.org/abs/2405.05689