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Main Authors: Giraldo, Marcela, Simonov, Arkadiy, Sim, Hasung, Lotfy, Ahmed Samir, Lilienblum, Martin, Forster, Lea, Gradauskaite, Elzbieta, Trassin, Morgan, Park, Je-Geun, Lottermoser, Thomas, Fiebig, Manfred
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2405.07457
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author Giraldo, Marcela
Simonov, Arkadiy
Sim, Hasung
Lotfy, Ahmed Samir
Lilienblum, Martin
Forster, Lea
Gradauskaite, Elzbieta
Trassin, Morgan
Park, Je-Geun
Lottermoser, Thomas
Fiebig, Manfred
author_facet Giraldo, Marcela
Simonov, Arkadiy
Sim, Hasung
Lotfy, Ahmed Samir
Lilienblum, Martin
Forster, Lea
Gradauskaite, Elzbieta
Trassin, Morgan
Park, Je-Geun
Lottermoser, Thomas
Fiebig, Manfred
contents The functionality of magnetoelectric multiferroics depends on the formation, size, and coupling of their magnetic and electric domains. Knowing the parameters guiding these criteria is a key effort in the emerging field of magnetoelectric domain engineering. Here we show, using a combination of piezoresponse-force microscopy, non-linear optics, and x-ray scattering, that the correlation length setting the size of the ferroelectric domains in the multiferroic hexagonal manganites can be engineered from the micron range down to a few unit cells under the substitution of Mn$^{3+}$ ions with Al$^{3+}$ ions. The magnetoelectric coupling mechanism between the antiferromagnetic Mn$^{3+}$ order and the distortive-ferroelectric order remains intact even at substantial replacement of Mn$^{3+}$ by Al$^{3+}$. Hence, chemical substitution proves to be an effective tool for domain-size engineering in one of the most studied classes of multiferroics.
format Preprint
id arxiv_https___arxiv_org_abs_2405_07457
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Magnetoelectric domain engineering from micrometer to Ångstrøm scales
Giraldo, Marcela
Simonov, Arkadiy
Sim, Hasung
Lotfy, Ahmed Samir
Lilienblum, Martin
Forster, Lea
Gradauskaite, Elzbieta
Trassin, Morgan
Park, Je-Geun
Lottermoser, Thomas
Fiebig, Manfred
Materials Science
The functionality of magnetoelectric multiferroics depends on the formation, size, and coupling of their magnetic and electric domains. Knowing the parameters guiding these criteria is a key effort in the emerging field of magnetoelectric domain engineering. Here we show, using a combination of piezoresponse-force microscopy, non-linear optics, and x-ray scattering, that the correlation length setting the size of the ferroelectric domains in the multiferroic hexagonal manganites can be engineered from the micron range down to a few unit cells under the substitution of Mn$^{3+}$ ions with Al$^{3+}$ ions. The magnetoelectric coupling mechanism between the antiferromagnetic Mn$^{3+}$ order and the distortive-ferroelectric order remains intact even at substantial replacement of Mn$^{3+}$ by Al$^{3+}$. Hence, chemical substitution proves to be an effective tool for domain-size engineering in one of the most studied classes of multiferroics.
title Magnetoelectric domain engineering from micrometer to Ångstrøm scales
topic Materials Science
url https://arxiv.org/abs/2405.07457