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Bibliographic Details
Main Authors: Kozioł, Karol, Rzadkiewicz, Jacek
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2405.09259
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author Kozioł, Karol
Rzadkiewicz, Jacek
author_facet Kozioł, Karol
Rzadkiewicz, Jacek
contents The $4d \to 3p$ x-ray transitions in Cu- and Ni-like tungsten ions have been studied theoretically. The multiconfiguration Dirac-Hartree-Fock (MCDHF) method and the large-scale relativistic configuration-interaction (CI) method have been employed in order to take into account electron correlation effects on the wavelengths and transition rates. It was found that the wavelengths and transition rates obtained from the MCDHF-CI method depend strongly on the size and the type of the active space used in the calculations. It has been found that extending the active space of orbitals without careful control of the configuration state function base does not always lead to good quality MCDHF-CI results for highly ionized tungsten ions.
format Preprint
id arxiv_https___arxiv_org_abs_2405_09259
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Multiconfiguration Dirac-Hartree-Fock and configuration-interaction study of $4d-3p$ x-ray transitions in Cu- and Ni-like tungsten ions
Kozioł, Karol
Rzadkiewicz, Jacek
Atomic Physics
The $4d \to 3p$ x-ray transitions in Cu- and Ni-like tungsten ions have been studied theoretically. The multiconfiguration Dirac-Hartree-Fock (MCDHF) method and the large-scale relativistic configuration-interaction (CI) method have been employed in order to take into account electron correlation effects on the wavelengths and transition rates. It was found that the wavelengths and transition rates obtained from the MCDHF-CI method depend strongly on the size and the type of the active space used in the calculations. It has been found that extending the active space of orbitals without careful control of the configuration state function base does not always lead to good quality MCDHF-CI results for highly ionized tungsten ions.
title Multiconfiguration Dirac-Hartree-Fock and configuration-interaction study of $4d-3p$ x-ray transitions in Cu- and Ni-like tungsten ions
topic Atomic Physics
url https://arxiv.org/abs/2405.09259