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Main Authors: Keßler, Philipp, Garcia-Gassull, Laura, Suter, Andreas, Prokscha, Thomas, Salman, Zaher, Khalyavin, Dmitry, Manuel, Pascal, Orlandi, Fabio, Mazin, Igor I., Valentı, Roser, Moser, Simon
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2405.10820
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author Keßler, Philipp
Garcia-Gassull, Laura
Suter, Andreas
Prokscha, Thomas
Salman, Zaher
Khalyavin, Dmitry
Manuel, Pascal
Orlandi, Fabio
Mazin, Igor I.
Valentı, Roser
Moser, Simon
author_facet Keßler, Philipp
Garcia-Gassull, Laura
Suter, Andreas
Prokscha, Thomas
Salman, Zaher
Khalyavin, Dmitry
Manuel, Pascal
Orlandi, Fabio
Mazin, Igor I.
Valentı, Roser
Moser, Simon
contents Altermagnets are a novel class of magnetic materials besides ferro- and antiferromagnets, where the interplay of lattice and spin symmetries produces a magnetic order that is staggered both in coordinate as well as momentum space. The metallic rutile oxide RuO$_2$, long believed to be a textbook Pauli paramagnet, recently emerged as a workhorse altermagnet when resonant X-ray and neutron scattering studies reported nonzero magnetic moments and long-range collinear order. While experiments on thin films seem consistent with altermagnetic behavior, the origin and size of magnetic moments in RuO$_2$ still remain controversial. Here we show that RuO$_2$ is nonmagnetic, regardless if as bulk or thin film. Employing muon spin spectroscopy as a highly sensitive probe of local magnetic moments complemented by density functional theory, we find at most $1.4 \times 10^{-4} $ $μ_B$/Ru in bulk RuO$_2$ and at most $7.5 \times 10^{-4}$ $μ_B$/Ru in epitaxial films. In their essence, these moments reflect the detection limit of our spectrometers and are orders of magnitude smaller than previously reported neutron results, i.e., the moments previously assumed to rationalize altermagnetic behavior. Our own neutron diffraction measurements on RuO$_2$ single crystals identify multiple scattering as a likely source for this discrepancy.
format Preprint
id arxiv_https___arxiv_org_abs_2405_10820
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Absence of magnetic order in RuO$_2$: insights from $μ$SR spectroscopy and neutron diffraction
Keßler, Philipp
Garcia-Gassull, Laura
Suter, Andreas
Prokscha, Thomas
Salman, Zaher
Khalyavin, Dmitry
Manuel, Pascal
Orlandi, Fabio
Mazin, Igor I.
Valentı, Roser
Moser, Simon
Materials Science
Altermagnets are a novel class of magnetic materials besides ferro- and antiferromagnets, where the interplay of lattice and spin symmetries produces a magnetic order that is staggered both in coordinate as well as momentum space. The metallic rutile oxide RuO$_2$, long believed to be a textbook Pauli paramagnet, recently emerged as a workhorse altermagnet when resonant X-ray and neutron scattering studies reported nonzero magnetic moments and long-range collinear order. While experiments on thin films seem consistent with altermagnetic behavior, the origin and size of magnetic moments in RuO$_2$ still remain controversial. Here we show that RuO$_2$ is nonmagnetic, regardless if as bulk or thin film. Employing muon spin spectroscopy as a highly sensitive probe of local magnetic moments complemented by density functional theory, we find at most $1.4 \times 10^{-4} $ $μ_B$/Ru in bulk RuO$_2$ and at most $7.5 \times 10^{-4}$ $μ_B$/Ru in epitaxial films. In their essence, these moments reflect the detection limit of our spectrometers and are orders of magnitude smaller than previously reported neutron results, i.e., the moments previously assumed to rationalize altermagnetic behavior. Our own neutron diffraction measurements on RuO$_2$ single crystals identify multiple scattering as a likely source for this discrepancy.
title Absence of magnetic order in RuO$_2$: insights from $μ$SR spectroscopy and neutron diffraction
topic Materials Science
url https://arxiv.org/abs/2405.10820