Hydrogen peroxide forms spontaneously in water (bulk, film, or microdroplet) via reduction of dissolved oxygen at solid-water interface

Fuente: arXiv
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Auteurs principaux: Eatoo, Muzzamil Ahmad, Mishra, Himanshu
Format: Preprint
Publié: 2024
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_version_ 1866913356001050624
author Eatoo, Muzzamil Ahmad
Mishra, Himanshu
author_facet Eatoo, Muzzamil Ahmad
Mishra, Himanshu
contents Zare and co-workers have recently claimed that hydrogen peroxide is spontaneously generated on the air-water interface of sprayed microdroplets, i.e., that H2O2 forms without an external energy source or co-reactant or catalyst. Specifically, they find that the H2O2(aq) concentration in sprayed microdroplets increases by a factor of 3.5 (or 2.5) as the spray chamber's relative humidity (RH) is changed from 15% to 50% (or from 15% to 95%). Building on these results, they imply causation for the seasonality of viral infections arising from the RH-dependent H2O2 generation in environmental microdroplets. Here, we present an alternative explanation for their observations.
format Preprint
id arxiv_https___arxiv_org_abs_2405_10971
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Hydrogen peroxide forms spontaneously in water (bulk, film, or microdroplet) via reduction of dissolved oxygen at solid-water interface
Eatoo, Muzzamil Ahmad
Mishra, Himanshu
Soft Condensed Matter
Chemical Physics
Zare and co-workers have recently claimed that hydrogen peroxide is spontaneously generated on the air-water interface of sprayed microdroplets, i.e., that H2O2 forms without an external energy source or co-reactant or catalyst. Specifically, they find that the H2O2(aq) concentration in sprayed microdroplets increases by a factor of 3.5 (or 2.5) as the spray chamber's relative humidity (RH) is changed from 15% to 50% (or from 15% to 95%). Building on these results, they imply causation for the seasonality of viral infections arising from the RH-dependent H2O2 generation in environmental microdroplets. Here, we present an alternative explanation for their observations.
title Hydrogen peroxide forms spontaneously in water (bulk, film, or microdroplet) via reduction of dissolved oxygen at solid-water interface
topic Soft Condensed Matter
Chemical Physics
url https://arxiv.org/abs/2405.10971