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Main Authors: Sun, Zhenyu, Su, Yueqi, Zhi, Aomiao, Gao, Zhicheng, Han, Xu, Wu, Kang, Bao, Lihong, Huang, Yuan, Shi, Youguo, Bai, Xuedong, Cheng, Peng, Chen, Lan, Wu, Kehui, Tian, Xuezeng, Wu, Changzheng, Feng, Baojie
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2405.11485
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author Sun, Zhenyu
Su, Yueqi
Zhi, Aomiao
Gao, Zhicheng
Han, Xu
Wu, Kang
Bao, Lihong
Huang, Yuan
Shi, Youguo
Bai, Xuedong
Cheng, Peng
Chen, Lan
Wu, Kehui
Tian, Xuezeng
Wu, Changzheng
Feng, Baojie
author_facet Sun, Zhenyu
Su, Yueqi
Zhi, Aomiao
Gao, Zhicheng
Han, Xu
Wu, Kang
Bao, Lihong
Huang, Yuan
Shi, Youguo
Bai, Xuedong
Cheng, Peng
Chen, Lan
Wu, Kehui
Tian, Xuezeng
Wu, Changzheng
Feng, Baojie
contents Multiferroic materials, which simultaneously exhibit ferroelectricity and magnetism, have attracted substantial attention due to their fascinating physical properties and potential technological applications. With the trends towards device miniaturization, there is an increasing demand for the persistence of multiferroicity in single-layer materials at elevated temperatures. Here, we report high-temperature multiferroicity in single-layer CuCrSe$_2$, which hosts room-temperature ferroelectricity and 120 K ferromagnetism. Notably, the ferromagnetic coupling in single-layer CuCrSe$_2$ is enhanced by the ferroelectricity-induced orbital shift of Cr atoms, which is distinct from both types I and II multiferroicity. These findings are supported by a combination of second-harmonic generation, piezo-response force microscopy, scanning transmission electron microscopy, magnetic, and Hall measurements. Our research provides not only an exemplary platform for delving into intrinsic magnetoelectric interactions at the single-layer limit but also sheds light on potential development of electronic and spintronic devices utilizing two-dimensional multiferroics.
format Preprint
id arxiv_https___arxiv_org_abs_2405_11485
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Evidence for Multiferroicity in Single-Layer CuCrSe$_2$
Sun, Zhenyu
Su, Yueqi
Zhi, Aomiao
Gao, Zhicheng
Han, Xu
Wu, Kang
Bao, Lihong
Huang, Yuan
Shi, Youguo
Bai, Xuedong
Cheng, Peng
Chen, Lan
Wu, Kehui
Tian, Xuezeng
Wu, Changzheng
Feng, Baojie
Materials Science
Multiferroic materials, which simultaneously exhibit ferroelectricity and magnetism, have attracted substantial attention due to their fascinating physical properties and potential technological applications. With the trends towards device miniaturization, there is an increasing demand for the persistence of multiferroicity in single-layer materials at elevated temperatures. Here, we report high-temperature multiferroicity in single-layer CuCrSe$_2$, which hosts room-temperature ferroelectricity and 120 K ferromagnetism. Notably, the ferromagnetic coupling in single-layer CuCrSe$_2$ is enhanced by the ferroelectricity-induced orbital shift of Cr atoms, which is distinct from both types I and II multiferroicity. These findings are supported by a combination of second-harmonic generation, piezo-response force microscopy, scanning transmission electron microscopy, magnetic, and Hall measurements. Our research provides not only an exemplary platform for delving into intrinsic magnetoelectric interactions at the single-layer limit but also sheds light on potential development of electronic and spintronic devices utilizing two-dimensional multiferroics.
title Evidence for Multiferroicity in Single-Layer CuCrSe$_2$
topic Materials Science
url https://arxiv.org/abs/2405.11485