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Main Authors: Xing, Kaijian, McEwen, Daniel, Zhao, Weiyao, Bake, Abdulhakim, Cortie, David, Liu, Jingying, Vu, Thi-Hai-Yen, Hone, James, Stacey, Alastair, Edmonds, Mark T., Watanabe, Kenji, Taniguchi, Takashi, Ou, Qingdong, Qi, Dong-Chen, Fuhrer, Michael S.
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2405.12830
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author Xing, Kaijian
McEwen, Daniel
Zhao, Weiyao
Bake, Abdulhakim
Cortie, David
Liu, Jingying
Vu, Thi-Hai-Yen
Hone, James
Stacey, Alastair
Edmonds, Mark T.
Watanabe, Kenji
Taniguchi, Takashi
Ou, Qingdong
Qi, Dong-Chen
Fuhrer, Michael S.
author_facet Xing, Kaijian
McEwen, Daniel
Zhao, Weiyao
Bake, Abdulhakim
Cortie, David
Liu, Jingying
Vu, Thi-Hai-Yen
Hone, James
Stacey, Alastair
Edmonds, Mark T.
Watanabe, Kenji
Taniguchi, Takashi
Ou, Qingdong
Qi, Dong-Chen
Fuhrer, Michael S.
contents Van der Waals electrode integration is a promising strategy to create near-perfect interfaces between metals and two-dimensional materials, with advantages such as eliminating Fermi-level pinning and reducing contact resistance. However, the lack of a simple, generalizable pick-and-place transfer technology has greatly hampered the wide use of this technique. We demonstrate the pick-and-place transfer of pre-fabricated electrodes from reusable polished hydrogenated diamond substrates without the use of any surface treatments or sacrificial layers. The technique enables transfer of large-scale arbitrary metal electrodes, as demonstrated by successful transfer of eight different elemental metals with work functions ranging from 4.22 to 5.65 eV. The mechanical transfer of metal electrodes from diamond onto van der Waals materials creates atomically smooth interfaces with no interstitial impurities or disorder, as observed with cross-sectional high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy. As a demonstration of its device application, we use the diamond-transfer technique to create metal contacts to monolayer transition metal dichalcogenide semiconductors with high-work-function Pd, low-work-function Ti, and semi metal Bi to create n- and p-type field-effect transistors with low Schottky barrier heights. We also extend this technology to other applications such as ambipolar transistor and optoelectronics, paving the way for new device architectures and high-performance devices.
format Preprint
id arxiv_https___arxiv_org_abs_2405_12830
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Pick-and-place transfer of arbitrary-metal electrodes for van der Waals device fabrication
Xing, Kaijian
McEwen, Daniel
Zhao, Weiyao
Bake, Abdulhakim
Cortie, David
Liu, Jingying
Vu, Thi-Hai-Yen
Hone, James
Stacey, Alastair
Edmonds, Mark T.
Watanabe, Kenji
Taniguchi, Takashi
Ou, Qingdong
Qi, Dong-Chen
Fuhrer, Michael S.
Applied Physics
Van der Waals electrode integration is a promising strategy to create near-perfect interfaces between metals and two-dimensional materials, with advantages such as eliminating Fermi-level pinning and reducing contact resistance. However, the lack of a simple, generalizable pick-and-place transfer technology has greatly hampered the wide use of this technique. We demonstrate the pick-and-place transfer of pre-fabricated electrodes from reusable polished hydrogenated diamond substrates without the use of any surface treatments or sacrificial layers. The technique enables transfer of large-scale arbitrary metal electrodes, as demonstrated by successful transfer of eight different elemental metals with work functions ranging from 4.22 to 5.65 eV. The mechanical transfer of metal electrodes from diamond onto van der Waals materials creates atomically smooth interfaces with no interstitial impurities or disorder, as observed with cross-sectional high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy. As a demonstration of its device application, we use the diamond-transfer technique to create metal contacts to monolayer transition metal dichalcogenide semiconductors with high-work-function Pd, low-work-function Ti, and semi metal Bi to create n- and p-type field-effect transistors with low Schottky barrier heights. We also extend this technology to other applications such as ambipolar transistor and optoelectronics, paving the way for new device architectures and high-performance devices.
title Pick-and-place transfer of arbitrary-metal electrodes for van der Waals device fabrication
topic Applied Physics
url https://arxiv.org/abs/2405.12830