Nonlinear Spectroscopy via Generalized Quantum Phase Estimation

Fuente: arXiv
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Main Authors: Loaiza, Ignacio, Motlagh, Danial, Hejazi, Kasra, Zini, Modjtaba Shokrian, Delgado, Alain, Arrazola, Juan Miguel
Format: Preprint
Published: 2024
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author Loaiza, Ignacio
Motlagh, Danial
Hejazi, Kasra
Zini, Modjtaba Shokrian
Delgado, Alain
Arrazola, Juan Miguel
author_facet Loaiza, Ignacio
Motlagh, Danial
Hejazi, Kasra
Zini, Modjtaba Shokrian
Delgado, Alain
Arrazola, Juan Miguel
contents Response theory has a successful history of connecting experimental observations with theoretical predictions. Of particular interest is the optical response of matter, from which spectroscopy experiments can be modelled. However, the calculation of response properties for quantum systems is often prohibitively expensive, especially for nonlinear spectroscopy, as it requires access to either the time evolution of the system or to excited states. In this work, we introduce a generalized quantum phase estimation framework designed for multi-variate phase estimation. This allows the treatment of general correlation functions enabling the recovery of response properties of arbitrary orders. The generalized quantum phase estimation circuit has an intuitive construction that is linked with a physical process of interest, and can directly sample frequencies from the distribution that would be obtained experimentally. In addition, we provide a single-ancilla modification of the new framework for early fault-tolerant quantum computers. Overall, our framework enables the efficient simulation of spectroscopy experiments beyond the linear regime, such as Raman spectroscopy, having that the circuit cost grows linearly with respect to the order of the target nonlinear response. This opens up an exciting new field of applications for quantum computers with potential technological impact.
format Preprint
id arxiv_https___arxiv_org_abs_2405_13885
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Nonlinear Spectroscopy via Generalized Quantum Phase Estimation
Loaiza, Ignacio
Motlagh, Danial
Hejazi, Kasra
Zini, Modjtaba Shokrian
Delgado, Alain
Arrazola, Juan Miguel
Quantum Physics
Response theory has a successful history of connecting experimental observations with theoretical predictions. Of particular interest is the optical response of matter, from which spectroscopy experiments can be modelled. However, the calculation of response properties for quantum systems is often prohibitively expensive, especially for nonlinear spectroscopy, as it requires access to either the time evolution of the system or to excited states. In this work, we introduce a generalized quantum phase estimation framework designed for multi-variate phase estimation. This allows the treatment of general correlation functions enabling the recovery of response properties of arbitrary orders. The generalized quantum phase estimation circuit has an intuitive construction that is linked with a physical process of interest, and can directly sample frequencies from the distribution that would be obtained experimentally. In addition, we provide a single-ancilla modification of the new framework for early fault-tolerant quantum computers. Overall, our framework enables the efficient simulation of spectroscopy experiments beyond the linear regime, such as Raman spectroscopy, having that the circuit cost grows linearly with respect to the order of the target nonlinear response. This opens up an exciting new field of applications for quantum computers with potential technological impact.
title Nonlinear Spectroscopy via Generalized Quantum Phase Estimation
topic Quantum Physics
url https://arxiv.org/abs/2405.13885