Momentum-resolved electronic structures and strong electronic correlations in graphene-like nitride superconductors

Fuente: arXiv
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Main Authors: Bi, Jiachang, Lin, Yu, Zhang, Qinghua, Liu, Zhanfeng, Zhang, Ziyun, Zhang, Ruyi, Yao, Xiong, Chen, Guoxin, Liu, Haigang, Huang, Yaobo, Sun, Yuanhe, Zhang, Hui, Sun, Zhe, Xiao, Shaozhu, Cao, Yanwei
Format: Preprint
Published: 2024
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author Bi, Jiachang
Lin, Yu
Zhang, Qinghua
Liu, Zhanfeng
Zhang, Ziyun
Zhang, Ruyi
Yao, Xiong
Chen, Guoxin
Liu, Haigang
Huang, Yaobo
Sun, Yuanhe
Zhang, Hui
Sun, Zhe
Xiao, Shaozhu
Cao, Yanwei
author_facet Bi, Jiachang
Lin, Yu
Zhang, Qinghua
Liu, Zhanfeng
Zhang, Ziyun
Zhang, Ruyi
Yao, Xiong
Chen, Guoxin
Liu, Haigang
Huang, Yaobo
Sun, Yuanhe
Zhang, Hui
Sun, Zhe
Xiao, Shaozhu
Cao, Yanwei
contents Although transition-metal nitrides have been widely applied for several decades, experimental investigations of their high-resolution electronic band structures are rare due to the lack of high-quality single-crystalline samples. Here, we report on the first momentum-resolved electronic band structures of titanium nitride (TiN) films, a remarkable nitride superconductor. The measurements of crystal structures and electrical transport properties confirmed the high quality of these films. More importantly, with a combination of high-resolution angle-resolved photoelectron spectroscopy and the first-principles calculations, the extracted Coulomb interaction strength of TiN films can be as large as 8.5 eV, whereas resonant photoemission spectroscopy yields a value of 6.26 eV. These large values of Coulomb interaction strength indicate that superconducting TiN is a strongly correlated system. Our results uncover the unexpected electronic correlations in transition-metal nitrides, potentially providing a perspective not only to understand their emergent quantum states but also to develop their applications in quantum devices.
format Preprint
id arxiv_https___arxiv_org_abs_2405_18150
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Momentum-resolved electronic structures and strong electronic correlations in graphene-like nitride superconductors
Bi, Jiachang
Lin, Yu
Zhang, Qinghua
Liu, Zhanfeng
Zhang, Ziyun
Zhang, Ruyi
Yao, Xiong
Chen, Guoxin
Liu, Haigang
Huang, Yaobo
Sun, Yuanhe
Zhang, Hui
Sun, Zhe
Xiao, Shaozhu
Cao, Yanwei
Materials Science
Strongly Correlated Electrons
Superconductivity
Although transition-metal nitrides have been widely applied for several decades, experimental investigations of their high-resolution electronic band structures are rare due to the lack of high-quality single-crystalline samples. Here, we report on the first momentum-resolved electronic band structures of titanium nitride (TiN) films, a remarkable nitride superconductor. The measurements of crystal structures and electrical transport properties confirmed the high quality of these films. More importantly, with a combination of high-resolution angle-resolved photoelectron spectroscopy and the first-principles calculations, the extracted Coulomb interaction strength of TiN films can be as large as 8.5 eV, whereas resonant photoemission spectroscopy yields a value of 6.26 eV. These large values of Coulomb interaction strength indicate that superconducting TiN is a strongly correlated system. Our results uncover the unexpected electronic correlations in transition-metal nitrides, potentially providing a perspective not only to understand their emergent quantum states but also to develop their applications in quantum devices.
title Momentum-resolved electronic structures and strong electronic correlations in graphene-like nitride superconductors
topic Materials Science
Strongly Correlated Electrons
Superconductivity
url https://arxiv.org/abs/2405.18150