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Main Authors: Bousquet, Eric, Fava, Mauro, Romestan, Zachary, Gómez-Ortiz, Fernando, McCabe, Emma E., Romero, Aldo H.
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2406.14684
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author Bousquet, Eric
Fava, Mauro
Romestan, Zachary
Gómez-Ortiz, Fernando
McCabe, Emma E.
Romero, Aldo H.
author_facet Bousquet, Eric
Fava, Mauro
Romestan, Zachary
Gómez-Ortiz, Fernando
McCabe, Emma E.
Romero, Aldo H.
contents Chirality refers to the asymmetry of objects that cannot be superimposed on their mirror image. It is a concept that exists in various scientific fields and has profound consequences. Although these are perhaps most widely recognized within biology, chemistry, and pharmacology, recent advances in chiral phonons, topological systems, crystal enantiomorphic materials, and magneto-chiral materials have brought this topic to the forefront of condensed matter physics research. Our review discusses the symmetry requirements and the features associated with structural chirality in inorganic materials. This allows us to explore the nature of phase transitions in these systems, the coupling between order parameters, and their impact on the material's physical properties. We highlight essential contributions to the field, particularly recent progress in the study of chiral phonons, altermagnetism, magnetochirality between others. Despite the rarity of naturally occurring inorganic chiral crystals, this review also highlights a significant knowledge gap, presenting challenges and opportunities for structural chirality mostly at the fundamental level, e.g., chiral displacive phase transitions and ferrochirality, possibilities of tuning and switching structural chirality by external means (electric, magnetic, or strain fields), whether chirality could be an independent order parameter, and whether structural chirality could be quantified, etc. Beyond simply summarising this field of research, this review aims to inspire further research in materials science by addressing future challenges, encouraging the exploration of chirality beyond traditional boundaries, and seeking the development of innovative materials with superior or new properties.
format Preprint
id arxiv_https___arxiv_org_abs_2406_14684
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Structural chirality and related properties in the periodic inorganic solids: Review and perspectives
Bousquet, Eric
Fava, Mauro
Romestan, Zachary
Gómez-Ortiz, Fernando
McCabe, Emma E.
Romero, Aldo H.
Materials Science
Other Condensed Matter
Chirality refers to the asymmetry of objects that cannot be superimposed on their mirror image. It is a concept that exists in various scientific fields and has profound consequences. Although these are perhaps most widely recognized within biology, chemistry, and pharmacology, recent advances in chiral phonons, topological systems, crystal enantiomorphic materials, and magneto-chiral materials have brought this topic to the forefront of condensed matter physics research. Our review discusses the symmetry requirements and the features associated with structural chirality in inorganic materials. This allows us to explore the nature of phase transitions in these systems, the coupling between order parameters, and their impact on the material's physical properties. We highlight essential contributions to the field, particularly recent progress in the study of chiral phonons, altermagnetism, magnetochirality between others. Despite the rarity of naturally occurring inorganic chiral crystals, this review also highlights a significant knowledge gap, presenting challenges and opportunities for structural chirality mostly at the fundamental level, e.g., chiral displacive phase transitions and ferrochirality, possibilities of tuning and switching structural chirality by external means (electric, magnetic, or strain fields), whether chirality could be an independent order parameter, and whether structural chirality could be quantified, etc. Beyond simply summarising this field of research, this review aims to inspire further research in materials science by addressing future challenges, encouraging the exploration of chirality beyond traditional boundaries, and seeking the development of innovative materials with superior or new properties.
title Structural chirality and related properties in the periodic inorganic solids: Review and perspectives
topic Materials Science
Other Condensed Matter
url https://arxiv.org/abs/2406.14684