Lone Pair Induced 1D Character and Weak Cation-anion Interactions: Two Ingredients for Low Thermal Conductivity in Mixed-anion Metal Chalcohalides

Fuente: arXiv

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	Shen, Xingchen, Pal, Koushik, Acharyya, Paribesh, Raveau, Bernard, Boullay, Philippe, Prestipino, Carmelo, Fujii, Susumu, Yang, Chun-Chuen, Tsao, I-Yu, Renaud, Adele, Lemoine, Pierric, Candolfi, Christophe, Guilmeau, Emmanuel
Format:	Preprint
Veröffentlicht:	2024
Schlagworte:	Materials Science
Online-Zugang:	Acceder al recurso
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Ähnliche Einträge

Accelerated Discovery of Crystalline Materials with Record Ultralow Lattice Thermal Conductivity via a Universal Descriptor
von: Shen, Xingchen, et al.
Veröffentlicht: (2025)

Evidence of Lone Pair Crafted Emphanisis in the Ruddlesden–Popper Halide Perovskite Cs2PbI2Cl2
von: Ivy Maria, et al.
Veröffentlicht: (2024)

Diffuson‐Dominated Thermal Transport Crossover From Ordered to Liquid‐Like Cu 3 BiS 3 : The Negligible Role of Ion Hopping
von: Jincheng Yue, et al.
Veröffentlicht: (2025)

Diffuson-Dominated Thermal Transport Crossover from Ordered to Liquid-like Cu$_3$BiS$_3$:The Negligible Role of Ion Hopping
von: Yue, Jincheng, et al.
Veröffentlicht: (2025)

Cation and anion monitoring in a wastewater treatment pilot project
von: Magda de Almeida
Veröffentlicht: (2015)

Absence of ground states for anions
von: Goto, Yukimi
Veröffentlicht: (2024)

Magnetic shielding in the atomic hydrogen anion
von: Kilich, Tymon, et al.
Veröffentlicht: (2025)

Monitoring of anionic surfactants in Ankara stream
von: Nervin Vural
Veröffentlicht: (1997)

The interplay of cation/anion and monovalent/divalent selectivity in negatively charged nanopores: local charge inversion and anion leakage
von: Lakics, Eszter, et al.
Veröffentlicht: (2026)

About the relevance of anion-π interactions in water.
von: Ballesteros-Garrido, Rafael, et al.
Veröffentlicht: (2026)

Simulating critical anion chemistry with indirect excitons
von: Myśliwy, Krzysztof, et al.
Veröffentlicht: (2024)

Isolated anions induced high ionic conductivity
von: Yang, Qifan, et al.
Veröffentlicht: (2024)

Photoionization of atoms and ions from endohedral anions
von: Dolmatov, V. K., et al.
Veröffentlicht: (2024)

El pensamiento filosófico de Engels : naturaleza y sociedad en la perspectiva teórica marxista / Giuseppe Prestipino
von: Giuseppe Prestipino
Veröffentlicht: (1977)

Perfil de Competencia Tecnológica: una propuesta para el sector de Energías Renovables
von: Norma Candolfi Arballo
Veröffentlicht: (2020)

Caracterización de anamorfos de Botryosphaeriaceae asociados a deterioro progresivo en vid (Vitis vinifera L.) aislados de la región vitivinícola de Baja California
von: Ofelia Candolfi Arballo
Veröffentlicht: (2009)

Metal‐to‐insulator transition in oxide semimetals by anion doping
von: Haitao Hong, et al.
Veröffentlicht: (2024)

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents
von: Alexander Rösler, et al.
Veröffentlicht: (2025)

Coupled cluster theory for positron binding in anions and polyatomic molecules
von: Riso, Rosario R., et al.
Veröffentlicht: (2026)

Variational quantum algorithm for anion exchange across electrolyzer membrane
von: Gubaev, Timur, et al.
Veröffentlicht: (2025)

Superconductivity in cubic La3Al with interstitial anionic electrons
von: Tu, Zhijun, et al.
Veröffentlicht: (2025)

Peierls-like distortion drives anion ordering in rutile TiOF
von: Nathan, Siddhartha S., et al.
Veröffentlicht: (2024)

Preparation and application of cardanol ether‐based anionic–nonionic surfactant
von: Hong Chen, et al.
Veröffentlicht: (2025)

Electron ptychography reveals a ferroelectricity dominated by anion displacements
von: KP, Harikrishnan, et al.
Veröffentlicht: (2024)

Unimolecular processes in diatomic carbon anions at high rotational excitation
von: Schmidt, Viviane C., et al.
Veröffentlicht: (2024)

Phosphate elution from anion‐exchange membranes in soil analysis
von: Suwei Xu, et al.
Veröffentlicht: (2025)

Lentiviral vector determinants of anion‐exchange chromatography elution heterogeneity
von: George Pamenter, et al.
Veröffentlicht: (2024)

Wormlike micelles containing hydrotrope and anionic double‐tailed surfactants
von: Tingli Que, et al.
Veröffentlicht: (2025)

Potassium intake to regulate sodium excretion? Don't forget the anion
von: Matthew A. Bailey
Veröffentlicht: (2025)

Cyanostilbenes as Selective Chloride Carriers Relying on CH‐anion Interactions
von: Anurag Singh, et al.
Veröffentlicht: (2025)

Nonlinear Optical Effects Modulated by Distinctive Monovalent Cations with Lone Electron Pairs in AGaI 4 (A = Ga + , In + )
von: Hao Huo, et al.
Veröffentlicht: (2025)

Formation of the long-lived parent anion upon electron attachment to menadione
von: Izadi, Farhad, et al.
Veröffentlicht: (2026)

Extended Hubbard Model realized in 2D clusters of molecular anions
von: Tong, Oliver, et al.
Veröffentlicht: (2025)

Recent advances in structural characterization of volume‐regulated anion channels (VRACs)
von: Erkan Karakas, et al.
Veröffentlicht: (2025)

Enrichment of full AAV capsids by preparative strong anion exchange chromatography
von: Suriyasri Subramanian, et al.
Veröffentlicht: (2025)

Robust and ultrathin pore‐filling anion exchange membranes for water electrolysis
von: Wenhao Zou, et al.
Veröffentlicht: (2025)

Adaptable platform for trapped cold electrons, hydrogen and lithium anions and cations
von: Azevedo, Levi O. A., et al.
Veröffentlicht: (2023)

A sea of soap: toxicity of anionic surfactant to Clytia hemisphaerica (Hydrozoa).
von: Ferrari, Valentina, et al.
Veröffentlicht: (2026)

Displacement of extracellular chloride by immobile anionic constituents of the brain's extracellular matrix
von: Kieran P. Normoyle, et al.
Veröffentlicht: (2024)

Correction to “The anti‐inflammatory and antiviral properties of anionic pulmonary surfactant phospholipids”
Veröffentlicht: (2024)

if (filemtime($filename) + $maxlifetime < time()) { unlink($filename); $count++; } } return $count; } /** * A function that is called internally when session data is to be saved. * * @param string $sessId The current session ID * @param string $data The session data to write * * @return bool */ protected function saveSession($sessId, $data): bool { $sessFile = $this->path . '/sess_' . $sessId; if ($handle = fopen($sessFile, 'w')) { $return = false; // Lock the file for exclusive access to avoid issues with multiple // processes writing session simultaneously: if (flock($handle, LOCK_EX)) { $return = fwrite($handle, $data); // Make sure that there's no trailing data by truncating the file to // the correct length: ftruncate($handle, strlen($data)); fflush($handle); flock($handle, LOCK_UN); } fclose($handle); if ($return !== false) { return true; } } // If we got this far, something went wrong with the file output... // It is tempting to throw an exception here, but this code is called // outside of the context of exception handling, so all we can do is // echo a message.

// Anecdotal testing Today and Yesterday seems to indicate destroy() // is called by the garbage collector and everything is good. // Something to keep in mind though. return 0; } /** * Write function that is called when session data is to be saved. * * @param string $sessId The current session ID * @param string $data The session data to write * * @return bool */ public function write($sessId, $data): bool { if ($this->writesDisabled) { return true; } return $this->saveSession($sessId, $data); } /** * A function that is called internally when session data is to be saved. * * @param string $sessId The current session ID * @param string $data The session data to write * * @return bool */ abstract protected function saveSession($sessId, $data): bool; }

* * @return void */ public function writeClose() { // The assumption is that we're using PHP's ext/session. // session_write_close() will actually overwrite $_SESSION with an // empty array on completion -- which leads to a mismatch between what // is in the storage object and $_SESSION. To get around this, we // temporarily reset $_SESSION to an array, and then re-link it to // the storage object. // // Additionally, while you _can_ write to $_SESSION following a // session_write_close() operation, no changes made to it will be // flushed to the session handler. As such, we now mark the storage // object isImmutable. $storage = $this->getStorage(); if (! $storage->isImmutable()) { $_SESSION = $storage->toArray(true); session_write_close(); $storage->fromArray($_SESSION); $storage->markImmutable(); } } /** * Attempt to set the session name * * If the session has already been started, or if the name provided fails * validation, an exception will be raised. * * @param string $name * @return SessionManager * @throws Exception\InvalidArgumentException */ public function setName($name) { if ($this->sessionExists()) { throw new Exception\InvalidArgumentException( 'Cannot set session name after a session has already started'

Environment & details:

GET Data empty

POST Data empty

Files empty

Key	Value
VUFIND_SESSION	"60b2b6c871811559aafcaaf59c609694"
language	"de"
ui	"standard"

Session

Key	Value
__Laminas	array:2 [`"_REQUEST_ACCESS_TIME" => 1790712641.1479 "_VALID" => array:1 [ "Laminas\Session\Validator\Id" => "60b2b6c871811559aafcaaf59c609694" ]`]
SessionState	Laminas\Stdlib\ArrayObject {#938}
FlashMessenger	Laminas\Stdlib\ArrayObject {#1433}
SessionHelper	Laminas\Stdlib\ArrayObject {#1759}

Server/Request Data

Key	Value
REDIRECT_VUFIND_LOCAL_DIR	"/usr/local/vufind/local"
REDIRECT_HTTPS	"on"
REDIRECT_SSL_TLS_SNI	"info.umar.mx"
REDIRECT_STATUS	"200"
VUFIND_LOCAL_DIR	"/usr/local/vufind/local"
HTTPS	"on"
SSL_TLS_SNI	"info.umar.mx"
HTTP_ACCEPT	"/"
HTTP_USER_AGENT	"Mozilla/5.0 AppleWebKit/537.36 (KHTML, like Gecko; compatible; ClaudeBot/1.0; +claudebot@anthropic.com)"
HTTP_COOKIE	"VUFIND_SESSION=60b2b6c871811559aafcaaf59c609694; language=de; ui=standard"
HTTP_ACCEPT_ENCODING	"gzip, br, zstd, deflate"
HTTP_HOST	"info.umar.mx"
PATH	"/usr/local/sbin:/usr/local/bin:/usr/sbin:/usr/bin:/snap/bin"
SERVER_SIGNATURE	"<address>Apache/2.4.66 (Ubuntu) Server at info.umar.mx Port 443</address>\n"
SERVER_SOFTWARE	"Apache/2.4.66 (Ubuntu)"
SERVER_NAME	"info.umar.mx"
SERVER_ADDR	"200.23.222.19"
SERVER_PORT	"443"
REMOTE_ADDR	"216.73.216.147"
DOCUMENT_ROOT	"/usr/local/vufind/public"
REQUEST_SCHEME	"https"
CONTEXT_PREFIX	""
CONTEXT_DOCUMENT_ROOT	"/usr/local/vufind/public"
SERVER_ADMIN	"admin@localhost"
SCRIPT_FILENAME	"/usr/local/vufind/public/index.php"
REMOTE_PORT	"26926"
REDIRECT_URL	""" /Record/\n arxiv_https___arxiv_org_abs_2406_16744/Similar """
GATEWAY_INTERFACE	"CGI/1.1"
SERVER_PROTOCOL	"HTTP/1.1"
REQUEST_METHOD	"GET"
QUERY_STRING	""
REQUEST_URI	"/Record/%0Aarxiv_https___arxiv_org_abs_2406_16744/Similar"
SCRIPT_NAME	"/index.php"
PHP_SELF	"/index.php"
REQUEST_TIME_FLOAT	1790712641.1429
REQUEST_TIME	1790712641

Environment Variables empty

Registered Handlers

0. Whoops\Handler\PrettyPageHandler