Molecular Nanomagnet $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ as Resource for Bipartite and Tripartite Quantum Entanglement and Coherence

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Auteurs principaux: Ghannadan, Azadeh, Zad, Hamid Arian, Haddadi, Saeed, Strečka, Jozef, Adamyan, Zhirayr, Ohanyan, Vadim
Format: Preprint
Publié: 2024
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author Ghannadan, Azadeh
Zad, Hamid Arian
Haddadi, Saeed
Strečka, Jozef
Adamyan, Zhirayr
Ohanyan, Vadim
author_facet Ghannadan, Azadeh
Zad, Hamid Arian
Haddadi, Saeed
Strečka, Jozef
Adamyan, Zhirayr
Ohanyan, Vadim
contents We investigate key quantum characteristics of the mixed spin-(1/2,1,1/2) Heisenberg trimer under the influence of an external magnetic field. Specifically, we analyze the distributions of bipartite and tripartite entanglement quantified through the respective negativities, and the $l_1$-norm of coherence with the help of rigorous analytical and numerical methods. Our findings suggest that the heterotrinuclear molecular nanomagnet $[\{\text{Cu}^\text{II}\text{L}\}_2\text{Ni}^\text{II}(\text{H}_2\text{O})_2](\text{ClO}_4)_{2} . 3\text{H}_2\text{O}$, which represents an experimental realization of the mixed spin-(1/2,1,1/2) Heisenberg trimer, exhibits a significant bipartite entanglement between $\text{Cu}^\text{II}$ and $\text{Ni}^\text{II}$ magnetic ions along with robust tripartite entanglement among all three constituent $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ magnetic ions. The significant bipartite and tripartite entanglement persists even at relatively high temperatures up to $37\,\text{K}$ and magnetic fields up to $46\,\text{T}$, whereby the coherence is maintained even at elevated temperatures. {It is evidenced that the aforementioned molecular complex with the magnetic core $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ provides an intriguing quantum resource, which exhibits a star-shaped state within the singlet eigenstate at low magnetic fields and W-like state within the triplet eigenstate at moderate magnetic fields.
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spellingShingle Molecular Nanomagnet $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ as Resource for Bipartite and Tripartite Quantum Entanglement and Coherence
Ghannadan, Azadeh
Zad, Hamid Arian
Haddadi, Saeed
Strečka, Jozef
Adamyan, Zhirayr
Ohanyan, Vadim
Quantum Physics
Statistical Mechanics
We investigate key quantum characteristics of the mixed spin-(1/2,1,1/2) Heisenberg trimer under the influence of an external magnetic field. Specifically, we analyze the distributions of bipartite and tripartite entanglement quantified through the respective negativities, and the $l_1$-norm of coherence with the help of rigorous analytical and numerical methods. Our findings suggest that the heterotrinuclear molecular nanomagnet $[\{\text{Cu}^\text{II}\text{L}\}_2\text{Ni}^\text{II}(\text{H}_2\text{O})_2](\text{ClO}_4)_{2} . 3\text{H}_2\text{O}$, which represents an experimental realization of the mixed spin-(1/2,1,1/2) Heisenberg trimer, exhibits a significant bipartite entanglement between $\text{Cu}^\text{II}$ and $\text{Ni}^\text{II}$ magnetic ions along with robust tripartite entanglement among all three constituent $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ magnetic ions. The significant bipartite and tripartite entanglement persists even at relatively high temperatures up to $37\,\text{K}$ and magnetic fields up to $46\,\text{T}$, whereby the coherence is maintained even at elevated temperatures. {It is evidenced that the aforementioned molecular complex with the magnetic core $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ provides an intriguing quantum resource, which exhibits a star-shaped state within the singlet eigenstate at low magnetic fields and W-like state within the triplet eigenstate at moderate magnetic fields.
title Molecular Nanomagnet $\text{Cu}^\text{II}\text{Ni}^\text{II}\text{Cu}^\text{II}$ as Resource for Bipartite and Tripartite Quantum Entanglement and Coherence
topic Quantum Physics
Statistical Mechanics
url https://arxiv.org/abs/2407.07037