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| Main Authors: | , , , , , |
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| Format: | Preprint |
| Published: |
2024
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2407.08142 |
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| _version_ | 1866914866335318016 |
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| author | Saito, Shota Numadate, Naoki Teraoka, Hidemasa Enami, Shinichi Kobayashi, Hirokazu Hama, Tetsuya |
| author_facet | Saito, Shota Numadate, Naoki Teraoka, Hidemasa Enami, Shinichi Kobayashi, Hirokazu Hama, Tetsuya |
| contents | Saturated fatty acids are abundant organic compounds in oceans and sea sprays. Their photochemical reactions induced by solar radiation have recently been discovered as an abiotic source of volatile organic compounds, which serve as precursors of secondary organic aerosols. However, photoabsorption of wavelengths longer than 250 nm in liquid saturated fatty acids remains unexplained, despite being first reported in 1931. Here we demonstrate that the previously reported absorption of wavelengths longer than 250 nm by liquid nonanoic acid [CH3(CH2)7COOH)] originates from traces of impurities (0.1% at most) intrinsically contained in nonanoic acid reagents. Absorption cross sections of nonanoic acid newly obtained here indicate that the upper limit of its photolysis rate is three-to-five orders of magnitude smaller than those for atmospherically relevant carbonyl compounds. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2407_08142 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Impurity contribution to ultraviolet absorption of saturated fatty acids Saito, Shota Numadate, Naoki Teraoka, Hidemasa Enami, Shinichi Kobayashi, Hirokazu Hama, Tetsuya Materials Science Saturated fatty acids are abundant organic compounds in oceans and sea sprays. Their photochemical reactions induced by solar radiation have recently been discovered as an abiotic source of volatile organic compounds, which serve as precursors of secondary organic aerosols. However, photoabsorption of wavelengths longer than 250 nm in liquid saturated fatty acids remains unexplained, despite being first reported in 1931. Here we demonstrate that the previously reported absorption of wavelengths longer than 250 nm by liquid nonanoic acid [CH3(CH2)7COOH)] originates from traces of impurities (0.1% at most) intrinsically contained in nonanoic acid reagents. Absorption cross sections of nonanoic acid newly obtained here indicate that the upper limit of its photolysis rate is three-to-five orders of magnitude smaller than those for atmospherically relevant carbonyl compounds. |
| title | Impurity contribution to ultraviolet absorption of saturated fatty acids |
| topic | Materials Science |
| url | https://arxiv.org/abs/2407.08142 |