Low Leakage Ferroelectric Heteroepitaxial Al$_{0.7}$Sc$_{0.3}$N Films on GaN

Fuente: arXiv
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Autores principales: Yazawa, Keisuke, Evans, Charles, Dickey, Elizabeth, Tellekamp, Brooks, Brennecka, Geoff L., Zakutayev, Andriy
Formato: Preprint
Publicado: 2024
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author Yazawa, Keisuke
Evans, Charles
Dickey, Elizabeth
Tellekamp, Brooks
Brennecka, Geoff L.
Zakutayev, Andriy
author_facet Yazawa, Keisuke
Evans, Charles
Dickey, Elizabeth
Tellekamp, Brooks
Brennecka, Geoff L.
Zakutayev, Andriy
contents Wurtzite (Al,Sc)N ferroelectrics are attractive for microelectronics applications due to their chemical and epitaxial structural compatibility with wurtzite semiconductors such as GaN and (Al,Ga)N. However, the leakage current in epitaxial stacks reported to date should be reduced for reliable device operation. Following the tradition of other semiconductor heterostructures, crystalline structural quality, as measured by breadth of diffraction peaks and correlating with dislocation density, is commonly used as a proxy for leakage current, but we demonstrate here that the crystalline mosaicity that dominates the broadening of diffraction peaks in epitaxial Al$_{0.7}$Sc$_{0.3}$N stacks does not dominate leakage current. We report here well-saturated ferroelectric hysteresis loops and orders of magnitude lower leakage current (0.07 A cm$^{-2}$) compared to values reported in literature (1 ~ 19 A cm$^{-2}$) for sputter-deposited epitaxial Al$_{0.7}$Sc$_{0.3}$N/GaN of comparable crystalline quality to prior reports. Further, we show Al$_{0.7}$Sc$_{0.3}$N on lattice-matched InGaN buffers with improved structural characteristics exhibits increased leakage characteristics. This demonstration and understanding can help to guide further efforts towards reliable wurtzite ferroelectric devices and prioritize approaches targeting further leakage current reduction.
format Preprint
id arxiv_https___arxiv_org_abs_2407_14037
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Low Leakage Ferroelectric Heteroepitaxial Al$_{0.7}$Sc$_{0.3}$N Films on GaN
Yazawa, Keisuke
Evans, Charles
Dickey, Elizabeth
Tellekamp, Brooks
Brennecka, Geoff L.
Zakutayev, Andriy
Applied Physics
Materials Science
Wurtzite (Al,Sc)N ferroelectrics are attractive for microelectronics applications due to their chemical and epitaxial structural compatibility with wurtzite semiconductors such as GaN and (Al,Ga)N. However, the leakage current in epitaxial stacks reported to date should be reduced for reliable device operation. Following the tradition of other semiconductor heterostructures, crystalline structural quality, as measured by breadth of diffraction peaks and correlating with dislocation density, is commonly used as a proxy for leakage current, but we demonstrate here that the crystalline mosaicity that dominates the broadening of diffraction peaks in epitaxial Al$_{0.7}$Sc$_{0.3}$N stacks does not dominate leakage current. We report here well-saturated ferroelectric hysteresis loops and orders of magnitude lower leakage current (0.07 A cm$^{-2}$) compared to values reported in literature (1 ~ 19 A cm$^{-2}$) for sputter-deposited epitaxial Al$_{0.7}$Sc$_{0.3}$N/GaN of comparable crystalline quality to prior reports. Further, we show Al$_{0.7}$Sc$_{0.3}$N on lattice-matched InGaN buffers with improved structural characteristics exhibits increased leakage characteristics. This demonstration and understanding can help to guide further efforts towards reliable wurtzite ferroelectric devices and prioritize approaches targeting further leakage current reduction.
title Low Leakage Ferroelectric Heteroepitaxial Al$_{0.7}$Sc$_{0.3}$N Films on GaN
topic Applied Physics
Materials Science
url https://arxiv.org/abs/2407.14037