Colloidal Clusters as models for chiral active micromotors

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Hauptverfasser: Biswas, Bipul, Kandula, Manasa
Format: Preprint
Veröffentlicht: 2024
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author Biswas, Bipul
Kandula, Manasa
author_facet Biswas, Bipul
Kandula, Manasa
contents Circular swimmers with tunable orbit radius and chirality are gaining attention due to their potential to illustrate novel collective phases in simulations and synthetic and biological active matter. Here, we present a facile experimental strategy for fabricating active rotors using chemically cross-linked clusters of Janus colloids. Janus clusters are propelled by induced charge electrophoresis in an alternating electric field. We demonstrate capillary-assisted assembly as a feasible path toward expanding the fabrication process to get large amounts of uniform circular clusters. Systematic studies of the Janus clusters reveal circular motion with tunable angular velocity, orbit radius, and chirality and a relation between the radius of gyration of the cluster and their rotational dynamics. Importantly, clusters with uniform azimuthal angles behave distinctly exhibiting larger orbit radii, while those with random angles exhibit higher angular velocities and smaller radii. We also validate the kinetic model for clusters beyond dimers. Collectively, our studies highlight that Janus clusters as promising candidates as controlled circular rotors with tunable properties and, hence in the future, will facilitate studies on the collective behaviors of synthetic chiral rotors.
format Preprint
id arxiv_https___arxiv_org_abs_2407_15061
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Colloidal Clusters as models for chiral active micromotors
Biswas, Bipul
Kandula, Manasa
Soft Condensed Matter
Circular swimmers with tunable orbit radius and chirality are gaining attention due to their potential to illustrate novel collective phases in simulations and synthetic and biological active matter. Here, we present a facile experimental strategy for fabricating active rotors using chemically cross-linked clusters of Janus colloids. Janus clusters are propelled by induced charge electrophoresis in an alternating electric field. We demonstrate capillary-assisted assembly as a feasible path toward expanding the fabrication process to get large amounts of uniform circular clusters. Systematic studies of the Janus clusters reveal circular motion with tunable angular velocity, orbit radius, and chirality and a relation between the radius of gyration of the cluster and their rotational dynamics. Importantly, clusters with uniform azimuthal angles behave distinctly exhibiting larger orbit radii, while those with random angles exhibit higher angular velocities and smaller radii. We also validate the kinetic model for clusters beyond dimers. Collectively, our studies highlight that Janus clusters as promising candidates as controlled circular rotors with tunable properties and, hence in the future, will facilitate studies on the collective behaviors of synthetic chiral rotors.
title Colloidal Clusters as models for chiral active micromotors
topic Soft Condensed Matter
url https://arxiv.org/abs/2407.15061