Quotient complex (QC)-based machine learning for 2D perovskite design

Fuente: arXiv
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Main Authors: Hu, Chuan-Shen, Mayengbam, Rishikanta, Xia, Kelin, Sum, Tze Chien
Format: Preprint
Published: 2024
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_version_ 1866910539998822400
author Hu, Chuan-Shen
Mayengbam, Rishikanta
Xia, Kelin
Sum, Tze Chien
author_facet Hu, Chuan-Shen
Mayengbam, Rishikanta
Xia, Kelin
Sum, Tze Chien
contents With remarkable stability and exceptional optoelectronic properties, two-dimensional (2D) halide layered perovskites hold immense promise for revolutionizing photovoltaic technology. Presently, inadequate representations have substantially impeded the design and discovery of 2D perovskites. In this context, we introduce a novel computational topology framework termed the quotient complex (QC), which serves as the foundation for the material representation. Our QC-based features are seamlessly integrated with learning models for the advancement of 2D perovskite design. At the heart of this framework lies the quotient complex descriptors (QCDs), representing a quotient variation of simplicial complexes derived from materials unit cell and periodic boundary conditions. Differing from prior material representations, this approach encodes higher-order interactions and periodicity information simultaneously. Based on the well-established New Materials for Solar Energetics (NMSE) databank, our QC-based machine learning models exhibit superior performance against all existing counterparts. This underscores the paramount role of periodicity information in predicting material functionality, while also showcasing the remarkable efficiency of the QC-based model in characterizing materials structural attributes.
format Preprint
id arxiv_https___arxiv_org_abs_2407_16996
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Quotient complex (QC)-based machine learning for 2D perovskite design
Hu, Chuan-Shen
Mayengbam, Rishikanta
Xia, Kelin
Sum, Tze Chien
Computational Engineering, Finance, and Science
Algebraic Topology
With remarkable stability and exceptional optoelectronic properties, two-dimensional (2D) halide layered perovskites hold immense promise for revolutionizing photovoltaic technology. Presently, inadequate representations have substantially impeded the design and discovery of 2D perovskites. In this context, we introduce a novel computational topology framework termed the quotient complex (QC), which serves as the foundation for the material representation. Our QC-based features are seamlessly integrated with learning models for the advancement of 2D perovskite design. At the heart of this framework lies the quotient complex descriptors (QCDs), representing a quotient variation of simplicial complexes derived from materials unit cell and periodic boundary conditions. Differing from prior material representations, this approach encodes higher-order interactions and periodicity information simultaneously. Based on the well-established New Materials for Solar Energetics (NMSE) databank, our QC-based machine learning models exhibit superior performance against all existing counterparts. This underscores the paramount role of periodicity information in predicting material functionality, while also showcasing the remarkable efficiency of the QC-based model in characterizing materials structural attributes.
title Quotient complex (QC)-based machine learning for 2D perovskite design
topic Computational Engineering, Finance, and Science
Algebraic Topology
url https://arxiv.org/abs/2407.16996