Statistical mechanics of frustrated assemblies and incompatible graphs

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Hauptverfasser: Ortiz-Tavárez, José M., Yang, Zhen, Kotov, Nicholas, Mao, Xiaoming
Format: Preprint
Veröffentlicht: 2024
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author Ortiz-Tavárez, José M.
Yang, Zhen
Kotov, Nicholas
Mao, Xiaoming
author_facet Ortiz-Tavárez, José M.
Yang, Zhen
Kotov, Nicholas
Mao, Xiaoming
contents Geometrically frustrated assemblies where building blocks misfit have been shown to generate intriguing phenomena from self-limited growth, fiber formation, to structural complexity. We introduce a graph theory formulation of geometrically frustrated assemblies, capturing frustrated interactions through the concept of incompatible flows, providing a direct link between structural connectivity and frustration. This theory offers a minimal yet comprehensive framework for the fundamental statistical mechanics of frustrated assemblies. Through numerical simulations, the theory reveals new characteristics of frustrated assemblies, including two distinct percolation transitions for structure and stress, a crossover between cumulative and non-cumulative frustration controlled by disorder, and a divergent length scale in their response.
format Preprint
id arxiv_https___arxiv_org_abs_2407_18210
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Statistical mechanics of frustrated assemblies and incompatible graphs
Ortiz-Tavárez, José M.
Yang, Zhen
Kotov, Nicholas
Mao, Xiaoming
Soft Condensed Matter
Disordered Systems and Neural Networks
Materials Science
Statistical Mechanics
Mathematical Physics
Geometrically frustrated assemblies where building blocks misfit have been shown to generate intriguing phenomena from self-limited growth, fiber formation, to structural complexity. We introduce a graph theory formulation of geometrically frustrated assemblies, capturing frustrated interactions through the concept of incompatible flows, providing a direct link between structural connectivity and frustration. This theory offers a minimal yet comprehensive framework for the fundamental statistical mechanics of frustrated assemblies. Through numerical simulations, the theory reveals new characteristics of frustrated assemblies, including two distinct percolation transitions for structure and stress, a crossover between cumulative and non-cumulative frustration controlled by disorder, and a divergent length scale in their response.
title Statistical mechanics of frustrated assemblies and incompatible graphs
topic Soft Condensed Matter
Disordered Systems and Neural Networks
Materials Science
Statistical Mechanics
Mathematical Physics
url https://arxiv.org/abs/2407.18210