Double-side Integration of the Fluorinated Self-Assembling Monolayers for Enhanced Stability of Inverted Perovskite Solar Cells
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2024
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| author | Ilicheva, Ekaterina A. Sukhorukova, Polina K. Luchnikov, Lev O. Balakirev, Dmitry O. Saratovsky, Nikita S. Morozov, Andrei P. Gostishchev, Pavel A. Yurchuk, S. Yu. Vasilev, Anton A. Kozlov, Sergey S. Didenko, Sergey I. Peregudova, Svetlana M. Muratov, Dmitry S. Luponosov, Yuriy N. Saranin, Danila S. |
| author_facet | Ilicheva, Ekaterina A. Sukhorukova, Polina K. Luchnikov, Lev O. Balakirev, Dmitry O. Saratovsky, Nikita S. Morozov, Andrei P. Gostishchev, Pavel A. Yurchuk, S. Yu. Vasilev, Anton A. Kozlov, Sergey S. Didenko, Sergey I. Peregudova, Svetlana M. Muratov, Dmitry S. Luponosov, Yuriy N. Saranin, Danila S. |
| contents | Traps and structural defects at the hole and electron transport interfaces of the microcrystalline absorber limits the efficiency and long-term stability of perovskite solar cells (PSCs) due to accumulation of the ionic clusters, non-radiative recombination and electrochemical corrosion. Surface engineering using self-assembled monolayers (SAM) was considered as an effective strategy for modification of charge-collection junctions. In this work, we demonstrate the first report about complex integration of a SAM for double-side passivation in p-i-n PSCs. Integrating the novel 5-(4-[bis(4-fluorophenyl)amino]phenyl)thiophene-2-carboxylic acid (FTPATC) as a fluorinated SAM at the hole-transport interface reduced potential barriers and lattice stresses in the absorber. At the electron-transport side, FTPATC interacted with the A-site cations of the perovskite molecule (Cs, formamidinium), inducing a dipole for defect compensation. Using the passivation approach with fluorinated SAM demonstrated benefits in the gain of the output performance up to 22.2%. The key-advantage of double-side passivation was confirmed by the enhanced stability under continuous light-soaking (1-sun equivalent, 65 C, ISOS-L-2), maintaining 88% of the initial performance over 1680 hours and thermal stabilization under harsh heating at 90 C. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2407_20690 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Double-side Integration of the Fluorinated Self-Assembling Monolayers for Enhanced Stability of Inverted Perovskite Solar Cells Ilicheva, Ekaterina A. Sukhorukova, Polina K. Luchnikov, Lev O. Balakirev, Dmitry O. Saratovsky, Nikita S. Morozov, Andrei P. Gostishchev, Pavel A. Yurchuk, S. Yu. Vasilev, Anton A. Kozlov, Sergey S. Didenko, Sergey I. Peregudova, Svetlana M. Muratov, Dmitry S. Luponosov, Yuriy N. Saranin, Danila S. Materials Science Mesoscale and Nanoscale Physics Traps and structural defects at the hole and electron transport interfaces of the microcrystalline absorber limits the efficiency and long-term stability of perovskite solar cells (PSCs) due to accumulation of the ionic clusters, non-radiative recombination and electrochemical corrosion. Surface engineering using self-assembled monolayers (SAM) was considered as an effective strategy for modification of charge-collection junctions. In this work, we demonstrate the first report about complex integration of a SAM for double-side passivation in p-i-n PSCs. Integrating the novel 5-(4-[bis(4-fluorophenyl)amino]phenyl)thiophene-2-carboxylic acid (FTPATC) as a fluorinated SAM at the hole-transport interface reduced potential barriers and lattice stresses in the absorber. At the electron-transport side, FTPATC interacted with the A-site cations of the perovskite molecule (Cs, formamidinium), inducing a dipole for defect compensation. Using the passivation approach with fluorinated SAM demonstrated benefits in the gain of the output performance up to 22.2%. The key-advantage of double-side passivation was confirmed by the enhanced stability under continuous light-soaking (1-sun equivalent, 65 C, ISOS-L-2), maintaining 88% of the initial performance over 1680 hours and thermal stabilization under harsh heating at 90 C. |
| title | Double-side Integration of the Fluorinated Self-Assembling Monolayers for Enhanced Stability of Inverted Perovskite Solar Cells |
| topic | Materials Science Mesoscale and Nanoscale Physics |
| url | https://arxiv.org/abs/2407.20690 |