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Bibliographic Details
Main Authors: Sheehan, Brendan C., Chen, Guanchu, Friedman, Jonathan R.
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2407.21214
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Table of Contents:
  • Clock transitions (CTs) in spin systems, which occur at avoided level crossings, enhance quantum coherence lifetimes T$_2$ because the transition becomes immune to the decohering effects of magnetic field fluctuations to first order. We present the first electron-spin resonance (ESR) characterization of CTs in certain defect-rich silica glasses, noting coherence times up to 16 $μ$s at the CTs. We find CT behavior at zero magnetic field in borosilicate and aluminosilicate glasses, but not in a variety of silica glasses lacking boron or aluminum. Annealing reduces or eliminates the zero-field signal. Since boron and aluminum have the same valence and are acceptors when substituted for silicon, we suggest the observed CT behavior could be generated by a spin-1 boron vacancy center within the borosilicate glass, and similarly, an aluminum-vacancy center in the aluminosilicate glass.