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Bibliographic Details
Main Authors: Dupuy, Mi-Song, Letournel, Eloïse, Levitt, Antoine
Format: Preprint
Published: 2024
Subjects:
Online Access:https://arxiv.org/abs/2408.00009
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author Dupuy, Mi-Song
Letournel, Eloïse
Levitt, Antoine
author_facet Dupuy, Mi-Song
Letournel, Eloïse
Levitt, Antoine
contents We consider the electrons of a molecule in the adiabatic time-dependent density functional theory approximation. We establish the well-posedness of the time evolution and its linear response close to a non-degenerate ground state, and prove the appearance of resonances at relevant frequencies. The main mathematical difficulty is due to the structure of the linearized equations, which are not complex-linear. We bypass this difficulty by reformulating the linearized problem as a real Hamiltonian system, whose stability is ensured by the second-order optimality conditions on the energy.
format Preprint
id arxiv_https___arxiv_org_abs_2408_00009
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Linear response and resonances in adiabatic time-dependent density functional theory
Dupuy, Mi-Song
Letournel, Eloïse
Levitt, Antoine
Analysis of PDEs
We consider the electrons of a molecule in the adiabatic time-dependent density functional theory approximation. We establish the well-posedness of the time evolution and its linear response close to a non-degenerate ground state, and prove the appearance of resonances at relevant frequencies. The main mathematical difficulty is due to the structure of the linearized equations, which are not complex-linear. We bypass this difficulty by reformulating the linearized problem as a real Hamiltonian system, whose stability is ensured by the second-order optimality conditions on the energy.
title Linear response and resonances in adiabatic time-dependent density functional theory
topic Analysis of PDEs
url https://arxiv.org/abs/2408.00009