Analytic Model for the Energy Spectrum of the Anharmonic Oscillator

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1. Verfasser: Caffarel, Michel
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Veröffentlicht: 2024
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author Caffarel, Michel
author_facet Caffarel, Michel
contents In a recent work we have proposed an original analytic expression for the partition function of the quartic oscillator. This partition function, which has a simple and compact form with {\it no adjustable parameters}, reproduces some key mathematical properties of the exact partition function and provides free energies accurate to a few percent over a wide range of temperatures and coupling constants. In this work, we present the derivation of the energy spectrum of this model. We also generalize our previous study limited to the quartic oscillator to the case of a general anharmonic oscillator. Numerical application for a potential of the form $V(x)=\frac{ω^2}{2} x^2 + g x^{2m}$ show that the energy levels are obtained with a relative error of about a few percent, a precision which we consider to be quite satisfactory given the simplicity of the model, the absence of adjustable parameters, and the negligible computational cost.
format Preprint
id arxiv_https___arxiv_org_abs_2408_01146
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Analytic Model for the Energy Spectrum of the Anharmonic Oscillator
Caffarel, Michel
Quantum Physics
Statistical Mechanics
Chemical Physics
In a recent work we have proposed an original analytic expression for the partition function of the quartic oscillator. This partition function, which has a simple and compact form with {\it no adjustable parameters}, reproduces some key mathematical properties of the exact partition function and provides free energies accurate to a few percent over a wide range of temperatures and coupling constants. In this work, we present the derivation of the energy spectrum of this model. We also generalize our previous study limited to the quartic oscillator to the case of a general anharmonic oscillator. Numerical application for a potential of the form $V(x)=\frac{ω^2}{2} x^2 + g x^{2m}$ show that the energy levels are obtained with a relative error of about a few percent, a precision which we consider to be quite satisfactory given the simplicity of the model, the absence of adjustable parameters, and the negligible computational cost.
title Analytic Model for the Energy Spectrum of the Anharmonic Oscillator
topic Quantum Physics
Statistical Mechanics
Chemical Physics
url https://arxiv.org/abs/2408.01146