Stimulated X-ray Raman scattering for selective preparation of dark states bypassing optical selection rules
Fuente:
arXiv
Gespeichert in:
| Hauptverfasser: | , , , , , |
|---|---|
| Format: | Preprint |
| Veröffentlicht: |
2024
|
| Schlagworte: | |
| Online-Zugang: | |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| _version_ | 1866913462078144512 |
|---|---|
| author | Montorsi, Francesco Mukamel, Shaul Tamassia, Filippo Garavelli, Marco Segatta, Francesco Nenov, Artur |
| author_facet | Montorsi, Francesco Mukamel, Shaul Tamassia, Filippo Garavelli, Marco Segatta, Francesco Nenov, Artur |
| contents | We present an X-ray based stimulated Raman approach to control the preparation of optically dark electronic states in generic molecular systems. Leveraging on the unique properties of core-level excited states, we demonstrate that optically forbidden transitions between singlet states, or between singlet and triplet states are made accessible. Two molecular systems are studied as a test-bed of the proposed approach, and its experimental feasibility is eventually discussed. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2408_04370 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Stimulated X-ray Raman scattering for selective preparation of dark states bypassing optical selection rules Montorsi, Francesco Mukamel, Shaul Tamassia, Filippo Garavelli, Marco Segatta, Francesco Nenov, Artur Chemical Physics Quantum Physics We present an X-ray based stimulated Raman approach to control the preparation of optically dark electronic states in generic molecular systems. Leveraging on the unique properties of core-level excited states, we demonstrate that optically forbidden transitions between singlet states, or between singlet and triplet states are made accessible. Two molecular systems are studied as a test-bed of the proposed approach, and its experimental feasibility is eventually discussed. |
| title | Stimulated X-ray Raman scattering for selective preparation of dark states bypassing optical selection rules |
| topic | Chemical Physics Quantum Physics |
| url | https://arxiv.org/abs/2408.04370 |