On the Liouville-von Neumann equation for unbounded Hamiltonians

Fuente: arXiv
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Auteurs principaux: Lonigro, Davide, Hahn, Alexander, Burgarth, Daniel
Format: Preprint
Publié: 2024
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author Lonigro, Davide
Hahn, Alexander
Burgarth, Daniel
author_facet Lonigro, Davide
Hahn, Alexander
Burgarth, Daniel
contents The evolution of mixed states of a closed quantum system is described by a group of evolution superoperators whose infinitesimal generator (the quantum Liouville superoperator, or Liouvillian) determines the mixed-state counterpart of the Schrödinger equation: the Liouville-von Neumann equation. When the state space of the system is infinite-dimensional, the Liouville superoperator is unbounded whenever the corresponding Hamiltonian is. In this paper, we provide a rigorous, pedagogically-oriented, and self-contained introduction to the quantum Liouville formalism in the presence of unbounded operators. We present and discuss a characterization of the domain of the Liouville superoperator originally due to M. Courbage; starting from that, we develop some simpler characterizations of the domain of the Liouvillian and its square. We also provide, with explicit proofs, some domains of essential self-adjointness (cores) of the Liouvillian.
format Preprint
id arxiv_https___arxiv_org_abs_2408_04980
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle On the Liouville-von Neumann equation for unbounded Hamiltonians
Lonigro, Davide
Hahn, Alexander
Burgarth, Daniel
Quantum Physics
Mathematical Physics
The evolution of mixed states of a closed quantum system is described by a group of evolution superoperators whose infinitesimal generator (the quantum Liouville superoperator, or Liouvillian) determines the mixed-state counterpart of the Schrödinger equation: the Liouville-von Neumann equation. When the state space of the system is infinite-dimensional, the Liouville superoperator is unbounded whenever the corresponding Hamiltonian is. In this paper, we provide a rigorous, pedagogically-oriented, and self-contained introduction to the quantum Liouville formalism in the presence of unbounded operators. We present and discuss a characterization of the domain of the Liouville superoperator originally due to M. Courbage; starting from that, we develop some simpler characterizations of the domain of the Liouvillian and its square. We also provide, with explicit proofs, some domains of essential self-adjointness (cores) of the Liouvillian.
title On the Liouville-von Neumann equation for unbounded Hamiltonians
topic Quantum Physics
Mathematical Physics
url https://arxiv.org/abs/2408.04980