Enhancement in neuromorphic NbO2 memristive device switching at cryogenic temperatures

Fuente: arXiv
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Auteurs principaux: Mburu, Ted, Robinson, Zachary R., Beckmann, Karsten, Lamba, Uday, Powell, Alex, Cady, Nathaniel, Sullivan, M. C.
Format: Preprint
Publié: 2024
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author Mburu, Ted
Robinson, Zachary R.
Beckmann, Karsten
Lamba, Uday
Powell, Alex
Cady, Nathaniel
Sullivan, M. C.
author_facet Mburu, Ted
Robinson, Zachary R.
Beckmann, Karsten
Lamba, Uday
Powell, Alex
Cady, Nathaniel
Sullivan, M. C.
contents The electrical properties and performance characteristics of niobium dioxide (NbO$_\mathrm{2}$)-based memristive devices are examined at cryogenic temperatures. Sub-stoichiometric Nb$_\mathrm{2}$O$_\mathrm{5}$ was deposited via magnetron sputtering and patterned in microscale (2$\times$2 - 15$\times$15 $μ$m$^2$) cross-bar Au/Ru/NbO$_\mathrm{x}$/Pt devices and electroformed at 3-5 V to make NbO$_\mathrm{2}$ filaments. At cryogenic temperatures, the threshold voltage ($V_\mathrm{th}$) increased by more than a factor of 3. The hold voltage ($V_\mathrm{h}$) was significantly lower than the threshold voltage for fast voltage sweeps (200 ms per measurement). If the sample is allowed to cool between voltage measurements, the hold voltage increases, but never reaches the threshold voltage, indicating the presence of non-volatile Nb$_\mathrm{2}$O$_\mathrm{5}$ in the filament. The devices have an activation energy of $E_a \approx 1.4$ eV, lower than other NbO$_\mathrm{2}$ devices reported. Our works shows that even nominally ``bad" memristive devices can be improved by reducing the leakage current and increases the sample resistance at cryogenic temperatures.
format Preprint
id arxiv_https___arxiv_org_abs_2408_06180
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Enhancement in neuromorphic NbO2 memristive device switching at cryogenic temperatures
Mburu, Ted
Robinson, Zachary R.
Beckmann, Karsten
Lamba, Uday
Powell, Alex
Cady, Nathaniel
Sullivan, M. C.
Applied Physics
Materials Science
The electrical properties and performance characteristics of niobium dioxide (NbO$_\mathrm{2}$)-based memristive devices are examined at cryogenic temperatures. Sub-stoichiometric Nb$_\mathrm{2}$O$_\mathrm{5}$ was deposited via magnetron sputtering and patterned in microscale (2$\times$2 - 15$\times$15 $μ$m$^2$) cross-bar Au/Ru/NbO$_\mathrm{x}$/Pt devices and electroformed at 3-5 V to make NbO$_\mathrm{2}$ filaments. At cryogenic temperatures, the threshold voltage ($V_\mathrm{th}$) increased by more than a factor of 3. The hold voltage ($V_\mathrm{h}$) was significantly lower than the threshold voltage for fast voltage sweeps (200 ms per measurement). If the sample is allowed to cool between voltage measurements, the hold voltage increases, but never reaches the threshold voltage, indicating the presence of non-volatile Nb$_\mathrm{2}$O$_\mathrm{5}$ in the filament. The devices have an activation energy of $E_a \approx 1.4$ eV, lower than other NbO$_\mathrm{2}$ devices reported. Our works shows that even nominally ``bad" memristive devices can be improved by reducing the leakage current and increases the sample resistance at cryogenic temperatures.
title Enhancement in neuromorphic NbO2 memristive device switching at cryogenic temperatures
topic Applied Physics
Materials Science
url https://arxiv.org/abs/2408.06180