Flexoelectricity versus Electrostatics in Polar Nematic Liquid Crystals

Fuente: arXiv
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Auteurs principaux: Paik, Lincoln, Selinger, Jonathan V.
Format: Preprint
Publié: 2024
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author Paik, Lincoln
Selinger, Jonathan V.
author_facet Paik, Lincoln
Selinger, Jonathan V.
contents Polar nematic liquid crystals have two special features, compared with conventional nematic liquid crystals. First, because of flexoelectricity, the combination of polar order and splay reduces the free energy. Second, because of electrostatics, any splay generates a bound charge density, which increases the free energy. To assess the competition between these two effects, we develop a theory that combines flexoelectricity and electrostatics. The theory predicts a phase diagram that includes ferroelectric, antiferroelectric, and conventional nematic phases.
format Preprint
id arxiv_https___arxiv_org_abs_2408_10347
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Flexoelectricity versus Electrostatics in Polar Nematic Liquid Crystals
Paik, Lincoln
Selinger, Jonathan V.
Soft Condensed Matter
Polar nematic liquid crystals have two special features, compared with conventional nematic liquid crystals. First, because of flexoelectricity, the combination of polar order and splay reduces the free energy. Second, because of electrostatics, any splay generates a bound charge density, which increases the free energy. To assess the competition between these two effects, we develop a theory that combines flexoelectricity and electrostatics. The theory predicts a phase diagram that includes ferroelectric, antiferroelectric, and conventional nematic phases.
title Flexoelectricity versus Electrostatics in Polar Nematic Liquid Crystals
topic Soft Condensed Matter
url https://arxiv.org/abs/2408.10347