Direct electrical access to the spin manifolds of individual monovalent lanthanide atoms

Fuente: arXiv
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Main Authors: Czap, Gregory, Noh, Kyungju, Velasco Jr., Jairo, Macfarlane, Roger M., Brune, Harald, Lutz, Christopher P.
Format: Preprint
Published: 2024
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author Czap, Gregory
Noh, Kyungju
Velasco Jr., Jairo
Macfarlane, Roger M.
Brune, Harald
Lutz, Christopher P.
author_facet Czap, Gregory
Noh, Kyungju
Velasco Jr., Jairo
Macfarlane, Roger M.
Brune, Harald
Lutz, Christopher P.
contents Lanthanide atoms show long magnetic lifetimes because of their strongly localized 4f electrons, but electrical control of their spins has been difficult because of their closed valence shell configurations. We achieved electron spin resonance of individual lanthanide atoms using a scanning tunneling microscope to probe the atoms bound to a protective insulating film. These atoms were prepared in the monovalent state with an unpaired 6s electron, enabling tunnel current to access their 4f electrons. Europium spectra display a rich array of transitions among the 54 combined electron and nuclear spin states. In contrast, samarium's ground state is a Kramers doublet with an extraordinarily large g-factor of nearly 5. These results demonstrate that all-electronic sensing and control of individual lanthanide spins is possible for quantum devices and spin-based electronics by using their rarely-observed monovalent cation state.
format Preprint
id arxiv_https___arxiv_org_abs_2408_11335
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Direct electrical access to the spin manifolds of individual monovalent lanthanide atoms
Czap, Gregory
Noh, Kyungju
Velasco Jr., Jairo
Macfarlane, Roger M.
Brune, Harald
Lutz, Christopher P.
Mesoscale and Nanoscale Physics
Atomic Physics
Chemical Physics
Lanthanide atoms show long magnetic lifetimes because of their strongly localized 4f electrons, but electrical control of their spins has been difficult because of their closed valence shell configurations. We achieved electron spin resonance of individual lanthanide atoms using a scanning tunneling microscope to probe the atoms bound to a protective insulating film. These atoms were prepared in the monovalent state with an unpaired 6s electron, enabling tunnel current to access their 4f electrons. Europium spectra display a rich array of transitions among the 54 combined electron and nuclear spin states. In contrast, samarium's ground state is a Kramers doublet with an extraordinarily large g-factor of nearly 5. These results demonstrate that all-electronic sensing and control of individual lanthanide spins is possible for quantum devices and spin-based electronics by using their rarely-observed monovalent cation state.
title Direct electrical access to the spin manifolds of individual monovalent lanthanide atoms
topic Mesoscale and Nanoscale Physics
Atomic Physics
Chemical Physics
url https://arxiv.org/abs/2408.11335