Excellent and CO$_2$$_{0.85}$Nd$_{0.1}$Cu$_{0.05}$O$_{2-δ}$-Nd$_x$Sr$_{1-x}$Fe$_{1-y}$Cu$_y$O$_{3-δ}$ dual-phase oxygen transport membranes
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arXiv
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| Format: | Preprint |
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2024
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| _version_ | 1866916365865058304 |
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| author | Zhang, Chao Zhu, Yue Wang, Xiaopeng Huang, Yanhao Zeng, Lingyong Li, Kuan Yu, Peifeng Wang, Kangwang Li, Longfu Xiang, Zaichen Chen, Rui Zhu, Xuefeng Luo, Huixia |
| author_facet | Zhang, Chao Zhu, Yue Wang, Xiaopeng Huang, Yanhao Zeng, Lingyong Li, Kuan Yu, Peifeng Wang, Kangwang Li, Longfu Xiang, Zaichen Chen, Rui Zhu, Xuefeng Luo, Huixia |
| contents | Oxygen transport membranes(OTMs)have provided great opportunities in the last decades but are suffering from the trade-off effect between stability and oxygen permeability. Here, we report a group of new planar dual-phase mixed ionic-electronic conducting (MIEC) OTMs consisting of CO$_2$$_{0.85}$Nd$_{0.1}$Cu$_{0.05}$O$_2$ (CNCO) and Nd$_x$Sr$_{1-x}$Fe$_{1-y}$Cu$_y$O$_3$(NSFCO; $x = 0.4, 0.6$; $y = 0.05, 0.1$) phases, showing excellent oxygen permeability while comparable CO$_2$-resistant stability. The substitution of Cu as a bifunctional additive decreases the sintering temperature and enhances bulk diffusion and oxygen permeability with the co-doping of Nd.The oxygen permeation fluxes reached 2.62 and 1.52 mL min$^{-1}$ cm$^{-2}$ at 1000$^\circ$C through the optimal 60wt%Ce0.85Nd0.1Cu0.05O2-40wt%Nd0.4Sr0.6Fe0.9Cu0.1O3 (CNCO-NSFCO41) composition with He and CO$_2$ sweeping, respectively, higher than all reported dense dual-phase OTMs. Such excellent CO$_2$-tolerant permeability meets the needs of potential industrial applications. Analysis with Zhu's oxygen permeation model shows lower bulk diffusion resistance of CNCO-NSFCO41 than that of reported 60wt%Ce0.85Pr0.1Cu0.05O2-40wt%Pr0.4Sr0.6Fe0.9Cu0.1O3(CPCO-PSFCO41)and more limitation by the interfacial exchange at high temperature. All the prepared OTMs also show good long-term stability over 100 hours in both atmospheres. Our results confirm the excellent oxygen permeability and stability under a high-concentration CO2 atmosphere, providing a material candidate for CO2 capture in oxyfuel combustion. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2408_12164 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Excellent and CO$_2$$_{0.85}$Nd$_{0.1}$Cu$_{0.05}$O$_{2-δ}$-Nd$_x$Sr$_{1-x}$Fe$_{1-y}$Cu$_y$O$_{3-δ}$ dual-phase oxygen transport membranes Zhang, Chao Zhu, Yue Wang, Xiaopeng Huang, Yanhao Zeng, Lingyong Li, Kuan Yu, Peifeng Wang, Kangwang Li, Longfu Xiang, Zaichen Chen, Rui Zhu, Xuefeng Luo, Huixia Materials Science Oxygen transport membranes(OTMs)have provided great opportunities in the last decades but are suffering from the trade-off effect between stability and oxygen permeability. Here, we report a group of new planar dual-phase mixed ionic-electronic conducting (MIEC) OTMs consisting of CO$_2$$_{0.85}$Nd$_{0.1}$Cu$_{0.05}$O$_2$ (CNCO) and Nd$_x$Sr$_{1-x}$Fe$_{1-y}$Cu$_y$O$_3$(NSFCO; $x = 0.4, 0.6$; $y = 0.05, 0.1$) phases, showing excellent oxygen permeability while comparable CO$_2$-resistant stability. The substitution of Cu as a bifunctional additive decreases the sintering temperature and enhances bulk diffusion and oxygen permeability with the co-doping of Nd.The oxygen permeation fluxes reached 2.62 and 1.52 mL min$^{-1}$ cm$^{-2}$ at 1000$^\circ$C through the optimal 60wt%Ce0.85Nd0.1Cu0.05O2-40wt%Nd0.4Sr0.6Fe0.9Cu0.1O3 (CNCO-NSFCO41) composition with He and CO$_2$ sweeping, respectively, higher than all reported dense dual-phase OTMs. Such excellent CO$_2$-tolerant permeability meets the needs of potential industrial applications. Analysis with Zhu's oxygen permeation model shows lower bulk diffusion resistance of CNCO-NSFCO41 than that of reported 60wt%Ce0.85Pr0.1Cu0.05O2-40wt%Pr0.4Sr0.6Fe0.9Cu0.1O3(CPCO-PSFCO41)and more limitation by the interfacial exchange at high temperature. All the prepared OTMs also show good long-term stability over 100 hours in both atmospheres. Our results confirm the excellent oxygen permeability and stability under a high-concentration CO2 atmosphere, providing a material candidate for CO2 capture in oxyfuel combustion. |
| title | Excellent and CO$_2$$_{0.85}$Nd$_{0.1}$Cu$_{0.05}$O$_{2-δ}$-Nd$_x$Sr$_{1-x}$Fe$_{1-y}$Cu$_y$O$_{3-δ}$ dual-phase oxygen transport membranes |
| topic | Materials Science |
| url | https://arxiv.org/abs/2408.12164 |