Thermodynamic limit on the open circuit voltage of solar cells

Fuente: arXiv
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Autore principale: Markvart, Tom
Natura: Preprint
Pubblicazione: 2024
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author Markvart, Tom
author_facet Markvart, Tom
contents A new thermodynamic limit for the open circuit voltage of solar cells that includes thermalization is obtained in terms of photon entropy. A simple graphical construction makes it possible to link this limit to the existing limits for single junction cells due to Trivich and Flinn, Shockley and Queisser and Würfel, and the thermodynamic Carnot-type limit for hot-carrier solar cell. At the fundamental level, this limit points to similarity between photovoltaic and thermoelectric energy conversion.
format Preprint
id arxiv_https___arxiv_org_abs_2409_02713
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Thermodynamic limit on the open circuit voltage of solar cells
Markvart, Tom
Optics
Statistical Mechanics
Applied Physics
A new thermodynamic limit for the open circuit voltage of solar cells that includes thermalization is obtained in terms of photon entropy. A simple graphical construction makes it possible to link this limit to the existing limits for single junction cells due to Trivich and Flinn, Shockley and Queisser and Würfel, and the thermodynamic Carnot-type limit for hot-carrier solar cell. At the fundamental level, this limit points to similarity between photovoltaic and thermoelectric energy conversion.
title Thermodynamic limit on the open circuit voltage of solar cells
topic Optics
Statistical Mechanics
Applied Physics
url https://arxiv.org/abs/2409.02713