Determination of the force transmission error in a single-sinker magnetic suspension densimeter due to the fluid-specific effect and its correction for use with gas mixtures containing oxygen

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Main Authors: Lozano-Martín, Daniel, Mondéjar, María E., Segovia, José J., Chamorro, César R.
Format: Preprint
Published: 2024
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author Lozano-Martín, Daniel
Mondéjar, María E.
Segovia, José J.
Chamorro, César R.
author_facet Lozano-Martín, Daniel
Mondéjar, María E.
Segovia, José J.
Chamorro, César R.
contents Density measurements from single-sinker magnetic suspension densimeters need to be corrected to compensate for the magnetic effects of the measuring cell materials and the fluid on the coupling transmission system. While the magnetic effect of the densimeter materials can be easily determined, the fluid effect requires the calculation of an apparatus-specific constant, $ε_ρ$. In this work, the apparatus-specific constant of the single-sinker magnetic suspension densimeter at the University of Valladolid has been determined by using two alternative methods. The first method, which uses density data for the same fluid and conditions and different sinkers, yielded a value of $ε_ρ$ = $4.6\cdot10^{-5}$. The second method, obtained from measurements with pure oxygen, yielded a value of $ε_ρ$ = $8.822\cdot10^{-5}$. The second value is considered as more reliable, as the first method presents inherent limitations in this case.
format Preprint
id arxiv_https___arxiv_org_abs_2409_07140
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Determination of the force transmission error in a single-sinker magnetic suspension densimeter due to the fluid-specific effect and its correction for use with gas mixtures containing oxygen
Lozano-Martín, Daniel
Mondéjar, María E.
Segovia, José J.
Chamorro, César R.
Chemical Physics
Density measurements from single-sinker magnetic suspension densimeters need to be corrected to compensate for the magnetic effects of the measuring cell materials and the fluid on the coupling transmission system. While the magnetic effect of the densimeter materials can be easily determined, the fluid effect requires the calculation of an apparatus-specific constant, $ε_ρ$. In this work, the apparatus-specific constant of the single-sinker magnetic suspension densimeter at the University of Valladolid has been determined by using two alternative methods. The first method, which uses density data for the same fluid and conditions and different sinkers, yielded a value of $ε_ρ$ = $4.6\cdot10^{-5}$. The second method, obtained from measurements with pure oxygen, yielded a value of $ε_ρ$ = $8.822\cdot10^{-5}$. The second value is considered as more reliable, as the first method presents inherent limitations in this case.
title Determination of the force transmission error in a single-sinker magnetic suspension densimeter due to the fluid-specific effect and its correction for use with gas mixtures containing oxygen
topic Chemical Physics
url https://arxiv.org/abs/2409.07140