Photo-induced molecular growth of benzonitrile in the gas phase

Fuente: arXiv
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Hauptverfasser: Behera, Nihar Ranjan, Kanakati, Arun Kumar, Thakkar, Pratikkumar, Payra, Siddhartha Sankar, Dutta, Saurav, Barik, Saroj, Lenka, Yash, Aravind, G
Format: Preprint
Veröffentlicht: 2024
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author Behera, Nihar Ranjan
Kanakati, Arun Kumar
Thakkar, Pratikkumar
Payra, Siddhartha Sankar
Dutta, Saurav
Barik, Saroj
Lenka, Yash
Aravind, G
author_facet Behera, Nihar Ranjan
Kanakati, Arun Kumar
Thakkar, Pratikkumar
Payra, Siddhartha Sankar
Dutta, Saurav
Barik, Saroj
Lenka, Yash
Aravind, G
contents Due to the absorption of high energetic ultraviolet (UV) photons by the surface layers of the cold molecular clouds, only low energetic photons are able to penetrate into the inner regions of these clouds. This leads to lower photo-ionization yield of molecules of higher ionization potential in these environments. However, here we have experimentally shown the ionization of Benzonitrile molecule using 266nm (4.66eV) photons. The low intensity and unfocused laser irradiation of benzonitrile molecules results extensive fragmentation. Moreover, the ion-neutral reactions among the cationic fragments and neutral fragments shows promising molecular mass growth.
format Preprint
id arxiv_https___arxiv_org_abs_2409_08590
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Photo-induced molecular growth of benzonitrile in the gas phase
Behera, Nihar Ranjan
Kanakati, Arun Kumar
Thakkar, Pratikkumar
Payra, Siddhartha Sankar
Dutta, Saurav
Barik, Saroj
Lenka, Yash
Aravind, G
Chemical Physics
Due to the absorption of high energetic ultraviolet (UV) photons by the surface layers of the cold molecular clouds, only low energetic photons are able to penetrate into the inner regions of these clouds. This leads to lower photo-ionization yield of molecules of higher ionization potential in these environments. However, here we have experimentally shown the ionization of Benzonitrile molecule using 266nm (4.66eV) photons. The low intensity and unfocused laser irradiation of benzonitrile molecules results extensive fragmentation. Moreover, the ion-neutral reactions among the cationic fragments and neutral fragments shows promising molecular mass growth.
title Photo-induced molecular growth of benzonitrile in the gas phase
topic Chemical Physics
url https://arxiv.org/abs/2409.08590