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Main Authors: Kaushik, Sonia, Raj, Rakhul, Gupta, Pooja, Venkatesh, R, Chumakov, Andrei, Schwartzkopf, Matthias, Reddy, V Raghavendra, Kumar, Dileep
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2409.10569
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author Kaushik, Sonia
Raj, Rakhul
Gupta, Pooja
Venkatesh, R
Chumakov, Andrei
Schwartzkopf, Matthias
Reddy, V Raghavendra
Kumar, Dileep
author_facet Kaushik, Sonia
Raj, Rakhul
Gupta, Pooja
Venkatesh, R
Chumakov, Andrei
Schwartzkopf, Matthias
Reddy, V Raghavendra
Kumar, Dileep
contents Organic spintronics has drawn the interest of the science community due to various applications in spin-valve devices. However, an efficient room-temperature Organic Spin Valve device has not been experimentally realized due to the complicated spin transport at the metal-organic interfaces. The present study focuses on a comprehensive understanding of the interfacial properties essential for advancing device performance and functionality. The structural and magnetic properties of the ultra-thin Cobalt (Co) films deposited on the fullerene (C60) layer are studied to investigate the origin of magnetic anisotropy in the metal-organic bilayer structures. Due to the mechanical softness of C60, penetration of ferromagnetic Co atoms inside the C60 film is confirmed by the X-ray reflectivity and Secondary Ion Mass Spectroscopy measurements. Grazing incidence small-angle X-ray scattering and atomic force microscopy provided information regarding the structural and morphological properties of the Co/C60 bilayers, angular dependent Magneto-optic Kerr effect measurements with varying Co layer thickness provided information about the growth-induced uniaxial magnetic anisotropy. In contrast to the inorganic silicon substrates, magnetic anisotropy in Co film tends to develop at 25 Å thickness on the C60 layer, which further increases with the thickness of Cobalt. The anomalous behavior in coercivity and remanence variation along the nominal hard axis is explained by a two-grain Stoner-Wohlfarth model with intergranular exchange coupling. It is further confirmed by a non-uniform spatial distribution of magnetic domains investigated through Kerr microscopy. These anomalies could be attributed to the distribution of magneto-crystalline anisotropy and inhomogeneous strain caused by the formation of a diffused layer at the Co/C60 interface.
format Preprint
id arxiv_https___arxiv_org_abs_2409_10569
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Growth-Induced Unconventional Magnetic Anisotropy in Co/Fullerene (C60) Bilayer Systems; Insights from a Two-Grain Stoner-Wohlfarth Model
Kaushik, Sonia
Raj, Rakhul
Gupta, Pooja
Venkatesh, R
Chumakov, Andrei
Schwartzkopf, Matthias
Reddy, V Raghavendra
Kumar, Dileep
Materials Science
Organic spintronics has drawn the interest of the science community due to various applications in spin-valve devices. However, an efficient room-temperature Organic Spin Valve device has not been experimentally realized due to the complicated spin transport at the metal-organic interfaces. The present study focuses on a comprehensive understanding of the interfacial properties essential for advancing device performance and functionality. The structural and magnetic properties of the ultra-thin Cobalt (Co) films deposited on the fullerene (C60) layer are studied to investigate the origin of magnetic anisotropy in the metal-organic bilayer structures. Due to the mechanical softness of C60, penetration of ferromagnetic Co atoms inside the C60 film is confirmed by the X-ray reflectivity and Secondary Ion Mass Spectroscopy measurements. Grazing incidence small-angle X-ray scattering and atomic force microscopy provided information regarding the structural and morphological properties of the Co/C60 bilayers, angular dependent Magneto-optic Kerr effect measurements with varying Co layer thickness provided information about the growth-induced uniaxial magnetic anisotropy. In contrast to the inorganic silicon substrates, magnetic anisotropy in Co film tends to develop at 25 Å thickness on the C60 layer, which further increases with the thickness of Cobalt. The anomalous behavior in coercivity and remanence variation along the nominal hard axis is explained by a two-grain Stoner-Wohlfarth model with intergranular exchange coupling. It is further confirmed by a non-uniform spatial distribution of magnetic domains investigated through Kerr microscopy. These anomalies could be attributed to the distribution of magneto-crystalline anisotropy and inhomogeneous strain caused by the formation of a diffused layer at the Co/C60 interface.
title Growth-Induced Unconventional Magnetic Anisotropy in Co/Fullerene (C60) Bilayer Systems; Insights from a Two-Grain Stoner-Wohlfarth Model
topic Materials Science
url https://arxiv.org/abs/2409.10569