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Main Authors: Jangra, Divya, De, Binoy Krishna, Sharma, Pragati, Chakraborty, Koushik, Parate, Shubham, Yogi, Arvind Kumar, Mittal, Ranjan, Gupta, Mayanak K, Nukala, Pavan, Velpula, Praveen Kumar, Sathe, Vasant G.
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2409.17570
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author Jangra, Divya
De, Binoy Krishna
Sharma, Pragati
Chakraborty, Koushik
Parate, Shubham
Yogi, Arvind Kumar
Mittal, Ranjan
Gupta, Mayanak K
Nukala, Pavan
Velpula, Praveen Kumar
Sathe, Vasant G.
author_facet Jangra, Divya
De, Binoy Krishna
Sharma, Pragati
Chakraborty, Koushik
Parate, Shubham
Yogi, Arvind Kumar
Mittal, Ranjan
Gupta, Mayanak K
Nukala, Pavan
Velpula, Praveen Kumar
Sathe, Vasant G.
contents The anisotropic light-matter interactions in 2D materials have garnered significant attention for their potential to develop futuristic polarization-based optoelectronic devices, such as photodetectors and photo-actuators. In this study, we investigate the polarization-dependent interactions in ferroelectric 3R alpha-In2Se3 using Angle-Resolved Polarized Raman Spectroscopy (ARPRS) with different excitation lasers. Our experimental findings supported by complementary Density Functional Theory calculations demonstrate that the light-matter interactions depend not only on the crystallographic orientation but also on the excitation energy. Scanning transmission electron microscopy (STEM) confirms the highly anisotropic 3R crystal structure of alpha-In2Se3. This anisotropy in crystal structure facilitates significant optical anisotropy, driven by a complex interplay of electron-photon and electron-phonon interactions, which is reflected in the complex nature of the Raman tensor elements. These anisotropy interactions extend to the materials electrical response under light illumination. Remarkably, the anisotropic photo-response can be tuned by both polarization and wavelength of the incident light, making In2Se3 a promising material for advanced polarization-sensitive photodetection applications.
format Preprint
id arxiv_https___arxiv_org_abs_2409_17570
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Wavelength-dependent anisotropic light-matter interaction in 2D ferroelectric In2Se3
Jangra, Divya
De, Binoy Krishna
Sharma, Pragati
Chakraborty, Koushik
Parate, Shubham
Yogi, Arvind Kumar
Mittal, Ranjan
Gupta, Mayanak K
Nukala, Pavan
Velpula, Praveen Kumar
Sathe, Vasant G.
Materials Science
Mesoscale and Nanoscale Physics
The anisotropic light-matter interactions in 2D materials have garnered significant attention for their potential to develop futuristic polarization-based optoelectronic devices, such as photodetectors and photo-actuators. In this study, we investigate the polarization-dependent interactions in ferroelectric 3R alpha-In2Se3 using Angle-Resolved Polarized Raman Spectroscopy (ARPRS) with different excitation lasers. Our experimental findings supported by complementary Density Functional Theory calculations demonstrate that the light-matter interactions depend not only on the crystallographic orientation but also on the excitation energy. Scanning transmission electron microscopy (STEM) confirms the highly anisotropic 3R crystal structure of alpha-In2Se3. This anisotropy in crystal structure facilitates significant optical anisotropy, driven by a complex interplay of electron-photon and electron-phonon interactions, which is reflected in the complex nature of the Raman tensor elements. These anisotropy interactions extend to the materials electrical response under light illumination. Remarkably, the anisotropic photo-response can be tuned by both polarization and wavelength of the incident light, making In2Se3 a promising material for advanced polarization-sensitive photodetection applications.
title Wavelength-dependent anisotropic light-matter interaction in 2D ferroelectric In2Se3
topic Materials Science
Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2409.17570