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Main Authors: Wines, Daniel, Ibrahim, Akram, Gudibandla, Nishwanth, Adel, Tehseen, Abel, Frank M., Jois, Sharadh, Saritas, Kayahan, Krogel, Jaron T., Yin, Li, Berlijn, Tom, Hanbicki, Aubrey T., Stephen, Gregory M., Friedman, Adam L., Krylyuk, Sergiy, Davydov, Albert V., Donovan, Brian, Jamer, Michelle E., Walker, Angela R. Hight, Choudhary, Kamal, Tavazza, Francesca, Ataca, Can
Format: Preprint
Published: 2024
Subjects:
Online Access:https://arxiv.org/abs/2409.19082
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author Wines, Daniel
Ibrahim, Akram
Gudibandla, Nishwanth
Adel, Tehseen
Abel, Frank M.
Jois, Sharadh
Saritas, Kayahan
Krogel, Jaron T.
Yin, Li
Berlijn, Tom
Hanbicki, Aubrey T.
Stephen, Gregory M.
Friedman, Adam L.
Krylyuk, Sergiy
Davydov, Albert V.
Donovan, Brian
Jamer, Michelle E.
Walker, Angela R. Hight
Choudhary, Kamal
Tavazza, Francesca
Ataca, Can
author_facet Wines, Daniel
Ibrahim, Akram
Gudibandla, Nishwanth
Adel, Tehseen
Abel, Frank M.
Jois, Sharadh
Saritas, Kayahan
Krogel, Jaron T.
Yin, Li
Berlijn, Tom
Hanbicki, Aubrey T.
Stephen, Gregory M.
Friedman, Adam L.
Krylyuk, Sergiy
Davydov, Albert V.
Donovan, Brian
Jamer, Michelle E.
Walker, Angela R. Hight
Choudhary, Kamal
Tavazza, Francesca
Ataca, Can
contents Two-dimensional (2D) 1T-VSe$_2$ has prompted significant interest due to the discrepancies regarding alleged ferromagnetism (FM) at room temperature, charge density wave (CDW) states and the interplay between the two. We employed a combined Diffusion Monte Carlo (DMC) and density functional theory (DFT) approach to accurately investigate the magnetic properties, CDW states, and their response to strain in monolayer 1T-VSe$_2$. Our calculations show the delicate competition between various phases, revealing critical insights into the relationship between their energetic and structural properties. We performed classical Monte Carlo simulations informed by our DMC and DFT results, and found the magnetic transition temperature ($T_c$) of the undistorted (non-CDW) FM phase to be 228 K and the distorted (CDW) phase to be 68 K. Additionally, we studied the response of biaxial strain on the energetic stability and magnetic properties of various phases of 2D 1T-VSe$_2$ and found that small amounts of strain can increase the $T_c$, suggesting a promising route for engineering and enhancing magnetic behavior. Finally, we synthesized 1T-VSe$_2$ and performed Raman spectroscopy measurements, which were in close agreement with our calculated results, validating our computational approach. Our work emphasizes the role of highly accurate DMC methods in advancing the understanding of monolayer 1T-VSe$_2$ and provides a robust framework for future studies of 2D magnetic materials.
format Preprint
id arxiv_https___arxiv_org_abs_2409_19082
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Quantum Monte Carlo and density functional theory study of strain and magnetism in 2D 1T-VSe$_2$ with charge density wave states
Wines, Daniel
Ibrahim, Akram
Gudibandla, Nishwanth
Adel, Tehseen
Abel, Frank M.
Jois, Sharadh
Saritas, Kayahan
Krogel, Jaron T.
Yin, Li
Berlijn, Tom
Hanbicki, Aubrey T.
Stephen, Gregory M.
Friedman, Adam L.
Krylyuk, Sergiy
Davydov, Albert V.
Donovan, Brian
Jamer, Michelle E.
Walker, Angela R. Hight
Choudhary, Kamal
Tavazza, Francesca
Ataca, Can
Materials Science
Strongly Correlated Electrons
Two-dimensional (2D) 1T-VSe$_2$ has prompted significant interest due to the discrepancies regarding alleged ferromagnetism (FM) at room temperature, charge density wave (CDW) states and the interplay between the two. We employed a combined Diffusion Monte Carlo (DMC) and density functional theory (DFT) approach to accurately investigate the magnetic properties, CDW states, and their response to strain in monolayer 1T-VSe$_2$. Our calculations show the delicate competition between various phases, revealing critical insights into the relationship between their energetic and structural properties. We performed classical Monte Carlo simulations informed by our DMC and DFT results, and found the magnetic transition temperature ($T_c$) of the undistorted (non-CDW) FM phase to be 228 K and the distorted (CDW) phase to be 68 K. Additionally, we studied the response of biaxial strain on the energetic stability and magnetic properties of various phases of 2D 1T-VSe$_2$ and found that small amounts of strain can increase the $T_c$, suggesting a promising route for engineering and enhancing magnetic behavior. Finally, we synthesized 1T-VSe$_2$ and performed Raman spectroscopy measurements, which were in close agreement with our calculated results, validating our computational approach. Our work emphasizes the role of highly accurate DMC methods in advancing the understanding of monolayer 1T-VSe$_2$ and provides a robust framework for future studies of 2D magnetic materials.
title Quantum Monte Carlo and density functional theory study of strain and magnetism in 2D 1T-VSe$_2$ with charge density wave states
topic Materials Science
Strongly Correlated Electrons
url https://arxiv.org/abs/2409.19082