Thermochromic Properties of 3C-, 6H- and 4H-SiC Polytypes up to 500$^\circ$C

Fuente: arXiv
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Main Authors: Ferro, Gabriel, Carole, Davy, Chaussende, Didier
Format: Preprint
Published: 2024
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author Ferro, Gabriel
Carole, Davy
Chaussende, Didier
author_facet Ferro, Gabriel
Carole, Davy
Chaussende, Didier
contents The thermochromic properties (color change with temperature) of n type doped SiC wafers of different polytypes (3C, 4H and 6H) have been investigated up to 500$^\circ$C under air. It was found that 3C-SiC color passes from bright yellow at room temperature to deep orangeat 500$^\circ$C leading to a color contrast ($Δ$E) as high as 64. The hexagonal polytypes undergo also a color change upon heating but far less pronounced, with $Δ$E values <20. All these semiconductors undergo band gap shrinkage upon heating which effect largely participated to the observed color change. This effect is very sensitive for 3C polytypesince its bandgap is already in the visible energy range at room temperature. The thermochromicity of 3C-SiC was found to be reversible thanks to its thermal stability and its resistance towards oxidation.
format Preprint
id arxiv_https___arxiv_org_abs_2410_08566
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Thermochromic Properties of 3C-, 6H- and 4H-SiC Polytypes up to 500$^\circ$C
Ferro, Gabriel
Carole, Davy
Chaussende, Didier
Materials Science
The thermochromic properties (color change with temperature) of n type doped SiC wafers of different polytypes (3C, 4H and 6H) have been investigated up to 500$^\circ$C under air. It was found that 3C-SiC color passes from bright yellow at room temperature to deep orangeat 500$^\circ$C leading to a color contrast ($Δ$E) as high as 64. The hexagonal polytypes undergo also a color change upon heating but far less pronounced, with $Δ$E values <20. All these semiconductors undergo band gap shrinkage upon heating which effect largely participated to the observed color change. This effect is very sensitive for 3C polytypesince its bandgap is already in the visible energy range at room temperature. The thermochromicity of 3C-SiC was found to be reversible thanks to its thermal stability and its resistance towards oxidation.
title Thermochromic Properties of 3C-, 6H- and 4H-SiC Polytypes up to 500$^\circ$C
topic Materials Science
url https://arxiv.org/abs/2410.08566