Density, speed of sound, refractive index and relative permittivity of methanol, propan-1-ol or pentan-1-ol + benzylamine liquid mixtures. Application of the Kirkwood-Fröhlich model
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| Formato: | Preprint |
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2024
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| author | Hevia, Fernando Alonso, Víctor Cobos, Ana González, Juan Antonio Sanz, Luis Felipe de la Fuente, Isaías García |
| author_facet | Hevia, Fernando Alonso, Víctor Cobos, Ana González, Juan Antonio Sanz, Luis Felipe de la Fuente, Isaías García |
| contents | Densities ($ρ$), speeds of sound ($c$), relative permittivities at 1 MHz ($\varepsilon_{\text{r}}$) and refractive indices at the sodium D-line ($n_{\text{D}}$) at $T$ = (293.15 K to 303.15 K) and $p$ = 0.1 MPa are reported for binary liquid mixtures alkan-1-ol + benzylamine. Methanol, propan-1-ol and pentan-1-ol are the alkan-1-ols studied in this work. The values of the excess molar volume ($V_{\text{m}}^{\text{E}}$), excess isentropic compressibility ($κ_S^{\text{E}}$), excess speed of sound ($c^{\text{E}}$), excess refractive index ($n_{\text{D}}^{\text{E}}$), excess relative permittivity ($\varepsilon_{\text{r}}^{\text{E}}$) and its temperature derivative ${(\partial{\varepsilon_{\text{r}}}/\partial T)}_p$ are calculated, and they are adjusted to Redlich-Kister polynomials. The $V_{\text{m}}^{\text{E}}$ values are negative, indicating a predominance of the solvation between unlike molecules and structural effects. $\varepsilon_{\text{r}}^{\text{E}}$ values indicate a positive contribution from the creation of (alkan-1-ol)-benzylamine interactions, and the positive value for the methanol mixture emphasises the importance of solvation. Calculations on excess molar refractions point out to weaker dispersive interactions than in the ideal mixture, which may be explained by the mentioned solvation effects. The Kirkwood-Fröhlich model has been applied to the mixtures, and the Kirkwood correlation factors suggest an important relative weight, especially in the methanol system, of linear-like molecules in the solutions, which is in accordance with the positive contribution of the formed multimers to $\varepsilon_{\text{r}}^{\text{E}}$ due to their good effective response to the electric field. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2410_09058 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | Density, speed of sound, refractive index and relative permittivity of methanol, propan-1-ol or pentan-1-ol + benzylamine liquid mixtures. Application of the Kirkwood-Fröhlich model Hevia, Fernando Alonso, Víctor Cobos, Ana González, Juan Antonio Sanz, Luis Felipe de la Fuente, Isaías García Chemical Physics Densities ($ρ$), speeds of sound ($c$), relative permittivities at 1 MHz ($\varepsilon_{\text{r}}$) and refractive indices at the sodium D-line ($n_{\text{D}}$) at $T$ = (293.15 K to 303.15 K) and $p$ = 0.1 MPa are reported for binary liquid mixtures alkan-1-ol + benzylamine. Methanol, propan-1-ol and pentan-1-ol are the alkan-1-ols studied in this work. The values of the excess molar volume ($V_{\text{m}}^{\text{E}}$), excess isentropic compressibility ($κ_S^{\text{E}}$), excess speed of sound ($c^{\text{E}}$), excess refractive index ($n_{\text{D}}^{\text{E}}$), excess relative permittivity ($\varepsilon_{\text{r}}^{\text{E}}$) and its temperature derivative ${(\partial{\varepsilon_{\text{r}}}/\partial T)}_p$ are calculated, and they are adjusted to Redlich-Kister polynomials. The $V_{\text{m}}^{\text{E}}$ values are negative, indicating a predominance of the solvation between unlike molecules and structural effects. $\varepsilon_{\text{r}}^{\text{E}}$ values indicate a positive contribution from the creation of (alkan-1-ol)-benzylamine interactions, and the positive value for the methanol mixture emphasises the importance of solvation. Calculations on excess molar refractions point out to weaker dispersive interactions than in the ideal mixture, which may be explained by the mentioned solvation effects. The Kirkwood-Fröhlich model has been applied to the mixtures, and the Kirkwood correlation factors suggest an important relative weight, especially in the methanol system, of linear-like molecules in the solutions, which is in accordance with the positive contribution of the formed multimers to $\varepsilon_{\text{r}}^{\text{E}}$ due to their good effective response to the electric field. |
| title | Density, speed of sound, refractive index and relative permittivity of methanol, propan-1-ol or pentan-1-ol + benzylamine liquid mixtures. Application of the Kirkwood-Fröhlich model |
| topic | Chemical Physics |
| url | https://arxiv.org/abs/2410.09058 |