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Auteurs principaux: Huang, Xinyuan, Qu, Yueqiao, Liao, Yu, Zheng, Qian, Liu, Ran, Chen, Yu, Liu, Liang, Wang, Junzhong, Yao, Gang
Format: Preprint
Publié: 2024
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Accès en ligne:https://arxiv.org/abs/2410.13372
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author Huang, Xinyuan
Qu, Yueqiao
Liao, Yu
Zheng, Qian
Liu, Ran
Chen, Yu
Liu, Liang
Wang, Junzhong
Yao, Gang
author_facet Huang, Xinyuan
Qu, Yueqiao
Liao, Yu
Zheng, Qian
Liu, Ran
Chen, Yu
Liu, Liang
Wang, Junzhong
Yao, Gang
contents The coexistence of high-temperature intrinsic ferromagnetic ordering, large magnetic anisotropy, along with novel mechanical properties such as ferroelasticity and flexibility, in experimental feasible two-dimensional (2D) crystals is greatly appealing for nanoscale spintronics. However, the progress in identifying such materials is limited. Here, by first-principles calculations, we report the findings of an extraordinary combination of the above qualities for the first time in a new 2D exfoliated FeSi nanosheet in the P4/nmm space group. Due to the strong anion-mediated superexchange interaction, the monolayer FeSi (ML-FeSi) exhibits a Curie temperature Tc as high as 830 K, surpassing the current experimental record (344 K for ML-Cr3Te4). Furthermore, including FeSi, such isostructural lattices all demonstrate exceptional softness, as evidenced by their ultra-low in-plane stiffness. Remarkably, the transition metal atom and square-shaped crystal form work together to give this family of ML materials unique properties that can transition from Ising-like 2D ferromagnets in FeSi, MnP, MnAs, CrP, FeI, and VAs to 2D-XY ones in CrAs, VP, and multiferroic MnGe and TiTe. Overall, our work highlights such 2D lattices as promising candidates in emerging multifunctional device applications and nontrivial topological spintronics.
format Preprint
id arxiv_https___arxiv_org_abs_2410_13372
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle High-temperature ferromagnetism and ferroelasticity in ultraflexible atomically thin square-shaped lattices
Huang, Xinyuan
Qu, Yueqiao
Liao, Yu
Zheng, Qian
Liu, Ran
Chen, Yu
Liu, Liang
Wang, Junzhong
Yao, Gang
Mesoscale and Nanoscale Physics
Materials Science
The coexistence of high-temperature intrinsic ferromagnetic ordering, large magnetic anisotropy, along with novel mechanical properties such as ferroelasticity and flexibility, in experimental feasible two-dimensional (2D) crystals is greatly appealing for nanoscale spintronics. However, the progress in identifying such materials is limited. Here, by first-principles calculations, we report the findings of an extraordinary combination of the above qualities for the first time in a new 2D exfoliated FeSi nanosheet in the P4/nmm space group. Due to the strong anion-mediated superexchange interaction, the monolayer FeSi (ML-FeSi) exhibits a Curie temperature Tc as high as 830 K, surpassing the current experimental record (344 K for ML-Cr3Te4). Furthermore, including FeSi, such isostructural lattices all demonstrate exceptional softness, as evidenced by their ultra-low in-plane stiffness. Remarkably, the transition metal atom and square-shaped crystal form work together to give this family of ML materials unique properties that can transition from Ising-like 2D ferromagnets in FeSi, MnP, MnAs, CrP, FeI, and VAs to 2D-XY ones in CrAs, VP, and multiferroic MnGe and TiTe. Overall, our work highlights such 2D lattices as promising candidates in emerging multifunctional device applications and nontrivial topological spintronics.
title High-temperature ferromagnetism and ferroelasticity in ultraflexible atomically thin square-shaped lattices
topic Mesoscale and Nanoscale Physics
Materials Science
url https://arxiv.org/abs/2410.13372