Static and Dynamic Electronic Properties of Weyl Semimetal NbP -- A Single Crystal $^{93}$Nb-NMR Study

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Main Authors: Kubo, Tetsuro, Yasuoka, Hiroshi, Kasinathan, Deepa, Ranjith, K. M., Schmidt, Marcus, Baenitz, Michael
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Published: 2024
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author Kubo, Tetsuro
Yasuoka, Hiroshi
Kasinathan, Deepa
Ranjith, K. M.
Schmidt, Marcus
Baenitz, Michael
author_facet Kubo, Tetsuro
Yasuoka, Hiroshi
Kasinathan, Deepa
Ranjith, K. M.
Schmidt, Marcus
Baenitz, Michael
contents Nuclear magnetic resonance (NMR) techniques have been used to study the static and dynamic microscopic properties of the Weyl semimetal NbP. From a complete analysis of the angular dependence of the $^{93}$Nb-NMR spectra in a single crystal, the parameters for the electric quadrupole interactions and the magnetic hyperfine interactions were determined to be $ν_{\rm Q} = 0.61$\,MHz, $η= 0.20$, $(K_{XX}, K_{YY}, K_{ZZ}) = (- 0.06, 0.11, - 0.11)$\% at 4.5\,K. The temperature and field dependence of the $^{93}$Nb Knight shift revealed a characteristic feature of the shape of the density of states with nearly massless fermions. We clearly observed a quantum oscillation of the Knight shift associated with the band structure, whose frequency was in good agreement with the previous bulk measurements. The temperature dependence of the spin-lattice relaxation rate, $1 / T_{1} T$, showed an almost constant behavior for $30 < T < 180$\,K, while a weak temperature dependence was observed below $\sim 30$\,K. This contrasts with the behavior observed in TaP and TaAs, where the $1 / T_{1} T$ measured by the $^{181}$Ta nuclear quadrupole resonance (NQR) shows $1 / T_{1} T \propto T^{2}$ and $T^{4}$ above approximately 30\,K. In TaP, the temperature dependent orbital hyperfine interaction plays a signficant role in nuclear relaxation, whereas this contribution is not observed in TaAs. Two-component spin echo oscillations were observed. The shorter-period oscillation is attributed to the origin of quadrupole coupling, while the longer-period oscillation indicates the presence of indirect nuclear spin-spin coupling, as discussed in other Weyl semimetal like TaP.
format Preprint
id arxiv_https___arxiv_org_abs_2410_13525
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Static and Dynamic Electronic Properties of Weyl Semimetal NbP -- A Single Crystal $^{93}$Nb-NMR Study
Kubo, Tetsuro
Yasuoka, Hiroshi
Kasinathan, Deepa
Ranjith, K. M.
Schmidt, Marcus
Baenitz, Michael
Strongly Correlated Electrons
Materials Science
Nuclear magnetic resonance (NMR) techniques have been used to study the static and dynamic microscopic properties of the Weyl semimetal NbP. From a complete analysis of the angular dependence of the $^{93}$Nb-NMR spectra in a single crystal, the parameters for the electric quadrupole interactions and the magnetic hyperfine interactions were determined to be $ν_{\rm Q} = 0.61$\,MHz, $η= 0.20$, $(K_{XX}, K_{YY}, K_{ZZ}) = (- 0.06, 0.11, - 0.11)$\% at 4.5\,K. The temperature and field dependence of the $^{93}$Nb Knight shift revealed a characteristic feature of the shape of the density of states with nearly massless fermions. We clearly observed a quantum oscillation of the Knight shift associated with the band structure, whose frequency was in good agreement with the previous bulk measurements. The temperature dependence of the spin-lattice relaxation rate, $1 / T_{1} T$, showed an almost constant behavior for $30 < T < 180$\,K, while a weak temperature dependence was observed below $\sim 30$\,K. This contrasts with the behavior observed in TaP and TaAs, where the $1 / T_{1} T$ measured by the $^{181}$Ta nuclear quadrupole resonance (NQR) shows $1 / T_{1} T \propto T^{2}$ and $T^{4}$ above approximately 30\,K. In TaP, the temperature dependent orbital hyperfine interaction plays a signficant role in nuclear relaxation, whereas this contribution is not observed in TaAs. Two-component spin echo oscillations were observed. The shorter-period oscillation is attributed to the origin of quadrupole coupling, while the longer-period oscillation indicates the presence of indirect nuclear spin-spin coupling, as discussed in other Weyl semimetal like TaP.
title Static and Dynamic Electronic Properties of Weyl Semimetal NbP -- A Single Crystal $^{93}$Nb-NMR Study
topic Strongly Correlated Electrons
Materials Science
url https://arxiv.org/abs/2410.13525