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Main Authors: Galano-Frutos, Juan José, Bergamasco, Luca, Vigo, Paolo, Morciano, Matteo, Fasano, Matteo, Pirolli, Davide, Chiavazzo, Eliodoro, de Rosa, Maria Cristina
Format: Preprint
Published: 2024
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Online Access:https://arxiv.org/abs/2410.14355
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author Galano-Frutos, Juan José
Bergamasco, Luca
Vigo, Paolo
Morciano, Matteo
Fasano, Matteo
Pirolli, Davide
Chiavazzo, Eliodoro
de Rosa, Maria Cristina
author_facet Galano-Frutos, Juan José
Bergamasco, Luca
Vigo, Paolo
Morciano, Matteo
Fasano, Matteo
Pirolli, Davide
Chiavazzo, Eliodoro
de Rosa, Maria Cristina
contents Aquaporins (AQPs) and aquaglyceroporins (AQGPs) play a crucial role in regulating water transport and solute selectivity across biological membranes. Besides their biological relevance, AQPs have at-tracted growing interest as models for the design of next-generation biomimetic membranes for water filtration. In this work, we present a pore-level Quantitative Structure-Activity Relationship (QSAR) approach that relates structural and physicochemical pore descriptors with experimentally reported water permeation rates across a set of AQ(G)Ps with high-resolution 3D structures. This data-driven methodology, presented here as a proof of concept, introduces a multi-feature framework for determining pore descriptors associated with water transport efficiency in AQ(G)Ps. Applied to two compiled permeation rate datasets, this framework recapitulates determinants previously reported in single-feature studies, while also highlighting additional pore descriptors that emerge as relevant in a multi-variable context. The insights gained through this approach may, in perspective, contribute to advancing the rational design of AQP-based filtration devices and to deepening the molecular understanding of the function of these valuable macromolecules in health and disease.
format Preprint
id arxiv_https___arxiv_org_abs_2410_14355
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Pore-level Quantitative Structure-Activity Relationship (QSAR) for Water Permeation Rate in Aquaporins
Galano-Frutos, Juan José
Bergamasco, Luca
Vigo, Paolo
Morciano, Matteo
Fasano, Matteo
Pirolli, Davide
Chiavazzo, Eliodoro
de Rosa, Maria Cristina
Biomolecules
Aquaporins (AQPs) and aquaglyceroporins (AQGPs) play a crucial role in regulating water transport and solute selectivity across biological membranes. Besides their biological relevance, AQPs have at-tracted growing interest as models for the design of next-generation biomimetic membranes for water filtration. In this work, we present a pore-level Quantitative Structure-Activity Relationship (QSAR) approach that relates structural and physicochemical pore descriptors with experimentally reported water permeation rates across a set of AQ(G)Ps with high-resolution 3D structures. This data-driven methodology, presented here as a proof of concept, introduces a multi-feature framework for determining pore descriptors associated with water transport efficiency in AQ(G)Ps. Applied to two compiled permeation rate datasets, this framework recapitulates determinants previously reported in single-feature studies, while also highlighting additional pore descriptors that emerge as relevant in a multi-variable context. The insights gained through this approach may, in perspective, contribute to advancing the rational design of AQP-based filtration devices and to deepening the molecular understanding of the function of these valuable macromolecules in health and disease.
title Pore-level Quantitative Structure-Activity Relationship (QSAR) for Water Permeation Rate in Aquaporins
topic Biomolecules
url https://arxiv.org/abs/2410.14355