The Detectability of CH$_4$/CO$_2$/CO and N$_2$O Biosignatures through Reflection Spectroscopy of Terrestrial Exoplanets

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Main Authors: Tokadjian, Armen, Hu, Renyu, Damiano, Mario
Format: Preprint
Published: 2024
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author Tokadjian, Armen
Hu, Renyu
Damiano, Mario
author_facet Tokadjian, Armen
Hu, Renyu
Damiano, Mario
contents The chemical makeup of Earth's atmosphere during the Archean (4 Ga-2.5 Ga) and Proterozoic eon (2.5 Ga-0.5 Ga) contrast considerably with the present-day: the Archean was rich in carbon dioxide and methane and the Proterozoic had potentially higher amounts of nitrous oxide. CO$_2$ and CH$_4$ in an Archean Earth analog may be a compelling biosignature because their coexistence implies methane replenishment at rates unlikely to be abiotic. However, CH$_4$ can also be produced through geological processes, and setting constraints on volcanic molecules like CO may help address this ambiguity. N$_2$O in a Proterozoic Earth analog may be evidence of life because N$_2$O production on Earth is mostly biological. Motivated by these ideas, we use the code $\mbox{ExoReL$^\Re$}$ to generate forward models and simulate spectral retrievals of an Archean and Proterozoic Earth-like planet to determine the detectability of CH$_4$, CO$_2$, CO, and N$_2$O in their reflected light spectrum for wavelength range 0.25-1.8 $μ$m. We show that it is challenging to detect CO in an Archean atmosphere for volume mixing ratio (VMR) $\leq$ 10%, but CH$_4$ is readily detectable for both the full wavelength span and truncated ranges cut at 1.7$μ$m and 1.6$μ$m, although for the latter two cases the dominant gas of the atmosphere is misidentified. Meanwhile, N$_2$O in a Proterozoic atmosphere is detectable for VMR=$10^{-3}$ and long wavelength cutoff $\geq 1.4μ$m, but undetectable for VMR $\leq 10^{-4}$ . The results presented here will be useful for the strategic design of the future Habitable Worlds Observatory and the components needed to potentially distinguish between inhabited and lifeless planets.
format Preprint
id arxiv_https___arxiv_org_abs_2410_14848
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle The Detectability of CH$_4$/CO$_2$/CO and N$_2$O Biosignatures through Reflection Spectroscopy of Terrestrial Exoplanets
Tokadjian, Armen
Hu, Renyu
Damiano, Mario
Earth and Planetary Astrophysics
The chemical makeup of Earth's atmosphere during the Archean (4 Ga-2.5 Ga) and Proterozoic eon (2.5 Ga-0.5 Ga) contrast considerably with the present-day: the Archean was rich in carbon dioxide and methane and the Proterozoic had potentially higher amounts of nitrous oxide. CO$_2$ and CH$_4$ in an Archean Earth analog may be a compelling biosignature because their coexistence implies methane replenishment at rates unlikely to be abiotic. However, CH$_4$ can also be produced through geological processes, and setting constraints on volcanic molecules like CO may help address this ambiguity. N$_2$O in a Proterozoic Earth analog may be evidence of life because N$_2$O production on Earth is mostly biological. Motivated by these ideas, we use the code $\mbox{ExoReL$^\Re$}$ to generate forward models and simulate spectral retrievals of an Archean and Proterozoic Earth-like planet to determine the detectability of CH$_4$, CO$_2$, CO, and N$_2$O in their reflected light spectrum for wavelength range 0.25-1.8 $μ$m. We show that it is challenging to detect CO in an Archean atmosphere for volume mixing ratio (VMR) $\leq$ 10%, but CH$_4$ is readily detectable for both the full wavelength span and truncated ranges cut at 1.7$μ$m and 1.6$μ$m, although for the latter two cases the dominant gas of the atmosphere is misidentified. Meanwhile, N$_2$O in a Proterozoic atmosphere is detectable for VMR=$10^{-3}$ and long wavelength cutoff $\geq 1.4μ$m, but undetectable for VMR $\leq 10^{-4}$ . The results presented here will be useful for the strategic design of the future Habitable Worlds Observatory and the components needed to potentially distinguish between inhabited and lifeless planets.
title The Detectability of CH$_4$/CO$_2$/CO and N$_2$O Biosignatures through Reflection Spectroscopy of Terrestrial Exoplanets
topic Earth and Planetary Astrophysics
url https://arxiv.org/abs/2410.14848