Surface Modifications of PCB-Based Plasma Sources Induced by Atmospheric Plasma: A Comparative Study of Dielectric and Electrode Materials

Fuente: arXiv
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Main Authors: Gail, Jonathan, Schmidt, Alisa, Thoma, Markus H.
Format: Preprint
Published: 2024
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author Gail, Jonathan
Schmidt, Alisa
Thoma, Markus H.
author_facet Gail, Jonathan
Schmidt, Alisa
Thoma, Markus H.
contents The study investigated the effects of atmospheric plasma on various dielectric materials (FR-4, PTFE, Al$_2$O$_3$) and electrode materials (copper, silver, gold-plated copper) used in surface micro-discharge plasma sources. XPS and laser microscopy were used to analyze changes in surface properties and chemical composition after 10 hours of plasma exposure. Al$_2$O$_3$ showed the highest resistance, with no significant changes in Al/O ratio or oxidation state. PTFE underwent oxidation, with fluorine substituted by oxygen, forming carbonyl, hydroxyl and aldehyde groups. FR-4 showed the most substantial changes, with etching of the epoxy matrix exposing glass fibers. This was in line with the XPS results, which show a higher O/C-ratio, less epoxy groups and higher nitrogen signals. Silver electrodes were most resilient, with sintered particles redistributed across the Al$_2$O$_3$ surface. Copper and gold-plated copper electrodes were more susceptible to oxidation and degradation, especially in areas exposed to plasma filaments. The results highlight the importance of carefully selecting materials based on resistance to plasma exposure and compatibility with the application.
format Preprint
id arxiv_https___arxiv_org_abs_2410_16751
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Surface Modifications of PCB-Based Plasma Sources Induced by Atmospheric Plasma: A Comparative Study of Dielectric and Electrode Materials
Gail, Jonathan
Schmidt, Alisa
Thoma, Markus H.
Plasma Physics
The study investigated the effects of atmospheric plasma on various dielectric materials (FR-4, PTFE, Al$_2$O$_3$) and electrode materials (copper, silver, gold-plated copper) used in surface micro-discharge plasma sources. XPS and laser microscopy were used to analyze changes in surface properties and chemical composition after 10 hours of plasma exposure. Al$_2$O$_3$ showed the highest resistance, with no significant changes in Al/O ratio or oxidation state. PTFE underwent oxidation, with fluorine substituted by oxygen, forming carbonyl, hydroxyl and aldehyde groups. FR-4 showed the most substantial changes, with etching of the epoxy matrix exposing glass fibers. This was in line with the XPS results, which show a higher O/C-ratio, less epoxy groups and higher nitrogen signals. Silver electrodes were most resilient, with sintered particles redistributed across the Al$_2$O$_3$ surface. Copper and gold-plated copper electrodes were more susceptible to oxidation and degradation, especially in areas exposed to plasma filaments. The results highlight the importance of carefully selecting materials based on resistance to plasma exposure and compatibility with the application.
title Surface Modifications of PCB-Based Plasma Sources Induced by Atmospheric Plasma: A Comparative Study of Dielectric and Electrode Materials
topic Plasma Physics
url https://arxiv.org/abs/2410.16751