Modulating outcomes of oil drops bursting at a water-air interface

Fuente: arXiv
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Autores principales: Kulkarni, Varun, Tamvada, Suhas, Lolla, Yashasvi Venkata, Anand, Sushant
Formato: Preprint
Publicado: 2024
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author Kulkarni, Varun
Tamvada, Suhas
Lolla, Yashasvi Venkata
Anand, Sushant
author_facet Kulkarni, Varun
Tamvada, Suhas
Lolla, Yashasvi Venkata
Anand, Sushant
contents Recent studies have shown that capillary waves generated by bursting of an oil drop at the water-air interface produces a daughter droplet inside the bath while part of it floats above it. Successive bursting events produce next generations of daughter droplets, gradually diminishing in size until the entire volume of oil rests atop the water-air interface. In this work, we demonstrate two different ways to modulate this process by modifying the constitution of the drop. Firstly, we introduce hydrophilic clay particles inside the parent oil drop and show that it arrests the cascade of daughter droplet generation preventing it from floating over the water-air interface. Secondly, we show that bursting behavior can be modified by a compound water-oil-air interface made of a film of oil with finite thickness and design a regime map which displays each of these outcomes. We underpin both of these demonstrations by theoretical arguments providing criteria to predict outcomes resulting therein. Lastly, all our scenarios have a direct relation to control of oil-water separation and stability of emulsified solutions in a wide variety of applications which include drug delivery, enhanced oil recovery, oil spills and food processing where a dispersed oil phase tries to separate from a continuous phase.
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id arxiv_https___arxiv_org_abs_2410_16961
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Modulating outcomes of oil drops bursting at a water-air interface
Kulkarni, Varun
Tamvada, Suhas
Lolla, Yashasvi Venkata
Anand, Sushant
Fluid Dynamics
Soft Condensed Matter
Recent studies have shown that capillary waves generated by bursting of an oil drop at the water-air interface produces a daughter droplet inside the bath while part of it floats above it. Successive bursting events produce next generations of daughter droplets, gradually diminishing in size until the entire volume of oil rests atop the water-air interface. In this work, we demonstrate two different ways to modulate this process by modifying the constitution of the drop. Firstly, we introduce hydrophilic clay particles inside the parent oil drop and show that it arrests the cascade of daughter droplet generation preventing it from floating over the water-air interface. Secondly, we show that bursting behavior can be modified by a compound water-oil-air interface made of a film of oil with finite thickness and design a regime map which displays each of these outcomes. We underpin both of these demonstrations by theoretical arguments providing criteria to predict outcomes resulting therein. Lastly, all our scenarios have a direct relation to control of oil-water separation and stability of emulsified solutions in a wide variety of applications which include drug delivery, enhanced oil recovery, oil spills and food processing where a dispersed oil phase tries to separate from a continuous phase.
title Modulating outcomes of oil drops bursting at a water-air interface
topic Fluid Dynamics
Soft Condensed Matter
url https://arxiv.org/abs/2410.16961