Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Shen, Pinrui, Booth, Donald, Liu, Chang, Beattie, Scott, Marceau, Claude, Shaffer, James P., Pawlak, Mariusz, Sadeghpour, H. R.
Format: Preprint
Veröffentlicht: 2024
Schlagworte:
Online-Zugang:https://arxiv.org/abs/2410.19129
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
_version_ 1866913599966937088
author Shen, Pinrui
Booth, Donald
Liu, Chang
Beattie, Scott
Marceau, Claude
Shaffer, James P.
Pawlak, Mariusz
Sadeghpour, H. R.
author_facet Shen, Pinrui
Booth, Donald
Liu, Chang
Beattie, Scott
Marceau, Claude
Shaffer, James P.
Pawlak, Mariusz
Sadeghpour, H. R.
contents We make absolute frequency measurements of Cs Rydberg transitions, $\vert 6S_{1/2}, F=3 \rangle \rightarrow \vert nS_{1/2}~(n=23\rm{-}90)\rangle$ and $\vert nD_{3/2,5/2}~(n=21\rm{-}90)\rangle$, with an accuracy of less than $ 72\,\rm kHz$. The quantum defect parameters for the measured Rydberg series are the most precise obtained to date. The quantum defect series is terminated at $δ_4$, showing that prior fits requiring higher order quantum defects reflect uncertainties in the observations. The precision of the measured quantum defects allow for the calculation of Rydberg electric-dipole transitions and fine-structure intervals extrapolated from high principal quantum numbers, to rival that of sophisticated many-body relativistic calculations carried out at low Rydberg principal quantum numbers. We quantitatively predict the contributions to the quantum defect parameters from core polarization and core penetration of Cs inner shell electrons. A new value for the ionization energy, consistent across the $ nS_{1/2}$ and $ nD_{3/2,5/2}$ Rydberg series, is reported at $31406.467 751 48 (14)~\rm{cm}^{-1}$.
format Preprint
id arxiv_https___arxiv_org_abs_2410_19129
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Ultra precise determination of Cs($nS_{1/2}$) and Cs($nD_J$) quantum defects for sensing and computing: Evaluation of core contributions
Shen, Pinrui
Booth, Donald
Liu, Chang
Beattie, Scott
Marceau, Claude
Shaffer, James P.
Pawlak, Mariusz
Sadeghpour, H. R.
Atomic Physics
Quantum Physics
We make absolute frequency measurements of Cs Rydberg transitions, $\vert 6S_{1/2}, F=3 \rangle \rightarrow \vert nS_{1/2}~(n=23\rm{-}90)\rangle$ and $\vert nD_{3/2,5/2}~(n=21\rm{-}90)\rangle$, with an accuracy of less than $ 72\,\rm kHz$. The quantum defect parameters for the measured Rydberg series are the most precise obtained to date. The quantum defect series is terminated at $δ_4$, showing that prior fits requiring higher order quantum defects reflect uncertainties in the observations. The precision of the measured quantum defects allow for the calculation of Rydberg electric-dipole transitions and fine-structure intervals extrapolated from high principal quantum numbers, to rival that of sophisticated many-body relativistic calculations carried out at low Rydberg principal quantum numbers. We quantitatively predict the contributions to the quantum defect parameters from core polarization and core penetration of Cs inner shell electrons. A new value for the ionization energy, consistent across the $ nS_{1/2}$ and $ nD_{3/2,5/2}$ Rydberg series, is reported at $31406.467 751 48 (14)~\rm{cm}^{-1}$.
title Ultra precise determination of Cs($nS_{1/2}$) and Cs($nD_J$) quantum defects for sensing and computing: Evaluation of core contributions
topic Atomic Physics
Quantum Physics
url https://arxiv.org/abs/2410.19129