Full interferometric map of the L1157 southern outflow: Formamide (NH$_2$CHO) can form in the gas, after all

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Autori principali: López-Sepulcre, Ana, Codella, Claudio, Ceccarelli, Cecilia, Podio, Linda, Robuschi, Juliette
Natura: Preprint
Pubblicazione: 2024
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author López-Sepulcre, Ana
Codella, Claudio
Ceccarelli, Cecilia
Podio, Linda
Robuschi, Juliette
author_facet López-Sepulcre, Ana
Codella, Claudio
Ceccarelli, Cecilia
Podio, Linda
Robuschi, Juliette
contents The formation mechanism of interstellar formamide (NH$_2$CHO), a key prebiotic precursor, is currently a matter of hot debate within the astrochemistry community, with both gas-phase and grain-surface chemical pathways having been proposed as its dominant formation route. The aim of the present study is to place firm observational constraints on the formation pathways leading to formamide thanks to new interferometric observations of the molecular outflow driven by the protostellar binary L1157. We employed the IRAM NOEMA interferometer to map the entire southern outflow of L1157, which contains three main shocked regions with increasing post-shock age: B0, B1, and B2. This allowed us to measure how the abundance of formamide, that of acetaldehyde (CH$_3$CHO), and the ratio of the two, vary with time in this region. In order to gain a greater understanding of the most likely formation routes of formamide, we ran a grid of astrochemical models and compared these to our observations. A comparison between observations and astrochemical modelling indicates that there are two possible scenarios: one in which the amount of formamide observed can be explained by gas-phase-only chemistry, and more specifically via the reaction H$_2$CO + NH$_2$ $\rightarrow$ NH$_2$CHO + H$_2$, and another in which part of the observed formamide originates from surface chemistry and part from gas-phase chemistry. Surface chemistry alone cannot account for the abundance of formamide that we measure. While grain-surface chemistry cannot be ruled out, the present study brings definitive proof that gas-phase chemistry does work in L1157-B and acts efficiently in the production of this molecular species.
format Preprint
id arxiv_https___arxiv_org_abs_2411_00495
institution arXiv
publishDate 2024
record_format arxiv
spellingShingle Full interferometric map of the L1157 southern outflow: Formamide (NH$_2$CHO) can form in the gas, after all
López-Sepulcre, Ana
Codella, Claudio
Ceccarelli, Cecilia
Podio, Linda
Robuschi, Juliette
Astrophysics of Galaxies
Solar and Stellar Astrophysics
The formation mechanism of interstellar formamide (NH$_2$CHO), a key prebiotic precursor, is currently a matter of hot debate within the astrochemistry community, with both gas-phase and grain-surface chemical pathways having been proposed as its dominant formation route. The aim of the present study is to place firm observational constraints on the formation pathways leading to formamide thanks to new interferometric observations of the molecular outflow driven by the protostellar binary L1157. We employed the IRAM NOEMA interferometer to map the entire southern outflow of L1157, which contains three main shocked regions with increasing post-shock age: B0, B1, and B2. This allowed us to measure how the abundance of formamide, that of acetaldehyde (CH$_3$CHO), and the ratio of the two, vary with time in this region. In order to gain a greater understanding of the most likely formation routes of formamide, we ran a grid of astrochemical models and compared these to our observations. A comparison between observations and astrochemical modelling indicates that there are two possible scenarios: one in which the amount of formamide observed can be explained by gas-phase-only chemistry, and more specifically via the reaction H$_2$CO + NH$_2$ $\rightarrow$ NH$_2$CHO + H$_2$, and another in which part of the observed formamide originates from surface chemistry and part from gas-phase chemistry. Surface chemistry alone cannot account for the abundance of formamide that we measure. While grain-surface chemistry cannot be ruled out, the present study brings definitive proof that gas-phase chemistry does work in L1157-B and acts efficiently in the production of this molecular species.
title Full interferometric map of the L1157 southern outflow: Formamide (NH$_2$CHO) can form in the gas, after all
topic Astrophysics of Galaxies
Solar and Stellar Astrophysics
url https://arxiv.org/abs/2411.00495