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| Main Authors: | , , , , , , , , |
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| Format: | Preprint |
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2024
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| Online Access: | https://arxiv.org/abs/2411.01440 |
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| _version_ | 1866916466051252224 |
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| author | Kundu, Anirban Jalali, Seyed Kamal Kim, Minhyeok Wang, Meihui Luo, Da Lee, Sun Hwa Pugno, Nicola M. Seong, Won Kyung Ruoff, Rodney S. |
| author_facet | Kundu, Anirban Jalali, Seyed Kamal Kim, Minhyeok Wang, Meihui Luo, Da Lee, Sun Hwa Pugno, Nicola M. Seong, Won Kyung Ruoff, Rodney S. |
| contents | Despite extensive microscale studies, the macroscopic mechanical properties of monolayer graphene remain underexplored. Here, we report the Young's modulus ($E$ = 1.11 $\pm$ 0.04 TPa), tensile strength ($σ$ = 27.40 $\pm$ 4.36 GPa), and failure strain ($ε_f$ = 6.01 $\pm$ 0.92 %) of centimeter-scale single-crystal monolayer graphene (SCG) 'dog bone' samples with edges aligned along the zigzag (zz) direction, supported by an ultra-thin polymer (polycarbonate) film. For samples with edges along the armchair (ac) direction, we obtain $E$ = 1.01 $\pm$ 0.10 TPa, $σ$ = 20.21 $\pm$ 3.22 GPa, $ε_f$ = 3.69 $\pm$ 0.38 %, and for chiral samples whose edges were between zz and ac, we obtain $E$= 0.75 $\pm$ 0.12 TPa, $σ$ = 23.56 $\pm$ 3.42 GPa, and $ε_f$ = 4.53 $\pm$ 0.40 %. The SCG is grown on single crystal Cu(111) foils by chemical vapor deposition (CVD). We used a home-built 'float-on-water' (FOW) tensile testing system for tensile loading measurements that also enabled in situ crack observation. The quantized fracture mechanics (QFM) analysis predicts an edge defect size from several to tens of nanometers based on chirality and notch angle. Through Weibull analysis and given that the fatal defects are confined on the edges of macroscale samples, we projected strength ranging from 13.67 to 18.43 GPa for an A4-size SCG according to their chirality. The exceptional mechanical performance of macroscale single crystal graphene (SCG) paves the way for its widespread use in a very wide variety of applications. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2411_01440 |
| institution | arXiv |
| publishDate | 2024 |
| record_format | arxiv |
| spellingShingle | The Mechanical Behavior of Macroscale Single-crystal Graphene Kundu, Anirban Jalali, Seyed Kamal Kim, Minhyeok Wang, Meihui Luo, Da Lee, Sun Hwa Pugno, Nicola M. Seong, Won Kyung Ruoff, Rodney S. Mesoscale and Nanoscale Physics Materials Science Despite extensive microscale studies, the macroscopic mechanical properties of monolayer graphene remain underexplored. Here, we report the Young's modulus ($E$ = 1.11 $\pm$ 0.04 TPa), tensile strength ($σ$ = 27.40 $\pm$ 4.36 GPa), and failure strain ($ε_f$ = 6.01 $\pm$ 0.92 %) of centimeter-scale single-crystal monolayer graphene (SCG) 'dog bone' samples with edges aligned along the zigzag (zz) direction, supported by an ultra-thin polymer (polycarbonate) film. For samples with edges along the armchair (ac) direction, we obtain $E$ = 1.01 $\pm$ 0.10 TPa, $σ$ = 20.21 $\pm$ 3.22 GPa, $ε_f$ = 3.69 $\pm$ 0.38 %, and for chiral samples whose edges were between zz and ac, we obtain $E$= 0.75 $\pm$ 0.12 TPa, $σ$ = 23.56 $\pm$ 3.42 GPa, and $ε_f$ = 4.53 $\pm$ 0.40 %. The SCG is grown on single crystal Cu(111) foils by chemical vapor deposition (CVD). We used a home-built 'float-on-water' (FOW) tensile testing system for tensile loading measurements that also enabled in situ crack observation. The quantized fracture mechanics (QFM) analysis predicts an edge defect size from several to tens of nanometers based on chirality and notch angle. Through Weibull analysis and given that the fatal defects are confined on the edges of macroscale samples, we projected strength ranging from 13.67 to 18.43 GPa for an A4-size SCG according to their chirality. The exceptional mechanical performance of macroscale single crystal graphene (SCG) paves the way for its widespread use in a very wide variety of applications. |
| title | The Mechanical Behavior of Macroscale Single-crystal Graphene |
| topic | Mesoscale and Nanoscale Physics Materials Science |
| url | https://arxiv.org/abs/2411.01440 |